Urea Montmorillonite-Extruded Nanocomposites: A Novel Slow-Release Material

被引:128
作者
Pereira, Elaine I. [2 ]
Minussi, Fernando B. [2 ]
da Cruz, Camila C. T. [2 ]
Bernardi, Alberto C. C. [3 ]
Ribeiro, Caue [1 ]
机构
[1] EMBRAPA Instrumentacao, BR-13560970 Sao Carlos, SP, Brazil
[2] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil
[3] EMBRAPA Pecuaria Sudeste, BR-13560970 Sao Carlos, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
urea; fertilizer; montmorillonite; extrusion; intercalation; REFRACTORY CASTABLES; SANDY SOIL; FERTILIZERS; RETENTION; ZEOLITE; KAOLIN; BIURET;
D O I
10.1021/jf3001229
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
The present study describes the preparation and characterization of a novel urea slow-release nanocomposite, based on urea intercalation into montmorillonite clay by an extrusion process at room temperature. Nanocomposites with urea contents ranging from 50 to 80 wt % were successfully produced and characterized. Analyses by XRD, DTA, and SEM-EDX confirmed the effectiveness of this simple process to exfoliate the clay lamellae into the urea matrix, forming a product that can be classified as a nanocomposite, due to the exfoliation degree attained. Diametral compression tests showed that the samples were very deformable, and the release rate of active components in water showed that the nanocomposite showed a slow release behavior for urea dissolution, even in low montmorillonite amounts (20% in weight).
引用
收藏
页码:5267 / 5272
页数:6
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