Covalent Capture of Nitrous Oxide by N-Heterocyclic Carbenes

被引：84

作者：

Tskhovrebov, Alexander G. ^{[1
]}

Solari, Euro ^{[1
]}

Wodrich, Matthew D. ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 01期

基金：

瑞士国家科学基金会;

关键词：

computational chemistry; heterocycles; N-heterocyclic carbenes; nitrogen oxides; structure elucidation; 3-COORDINATE MOLYBDENUM(III); DENSITY FUNCTIONALS; CHEMISTRY; BINDING; N2O; OXIDATION; CLEAVAGE; BOND;

D O I：

10.1002/anie.201106589

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A good catch: N-Heterocyclic carbenes (NHCs) form stable adducts with nitrous oxide (N 2O) under mild reaction conditions. The adducts display unique reactivity as evidenced by an alkylation reaction which leads to a rupture of the N-N bond. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：232 / 234

页数：3

共 48 条

[1]

[Anonymous], 2011, ANGEW CHEM

[2]

[Anonymous], 2010, ANGEW CHEM

[3]

[Anonymous], 2010, ANGEW CHEM

[4]

[Anonymous], Z NATURFORSCH B

[5]

[Anonymous], B CHEM SOC JPN

[6] Experimental and theoretical studies on the thermal decomposition of heterocyclic nitrosimines [J].

Bartsch, RA ;

Chae, YM ;

Ham, S ;

Birney, DM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (31) :7479-7486

[7] Critical analysis and extension of the Hirshfeld atoms in molecules [J].

Bultinck, Patrick ;

Van Alsenoy, Christian ;

Ayers, Paul W. ;

Carbo-Dorca, Ramon .

JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (14)

[8] Depletion of the Ozone Layer in the 21st Century [J].

Dameris, Martin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (03) :489-491

[9] GAUSSIAN-BASIS SETS FOR USE IN CORRELATED MOLECULAR CALCULATIONS .1. THE ATOMS BORON THROUGH NEON AND HYDROGEN [J].

DUNNING, TH .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (02) :1007-1023

[10] Reversible carboxylation of N-heterocyclic carbenes [J].

Duong, HA ;

Tekavec, TN ;

Arif, AM ;

Louie, J .

CHEMICAL COMMUNICATIONS, 2004, (01) :112-113

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