Studies of charge transfer at liquid | liquid interfaces and bilayer lipid membranes by scanning electrochemical microscopy

被引：100

作者：

Amemiya, S ^{[1
]}

Ding, ZF ^{[1
]}

Zhou, JF ^{[1
]}

Bard, AJ ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2000年 / 483卷 / 1-2期

基金：

美国国家科学基金会; 日本学术振兴会;

关键词：

scanning electrochemical microscopy; bilayer lipid membranes; electron transfer; immiscible electrolyte solutions;

D O I：

10.1016/S0022-0728(00)00021-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The principles of scanning electrochemical microscopy (SECM) and its application to studies of electron transfer at the interface between two immiscible electrolyte solutions are reviewed. The results of SECM measurements with a number of redox couples at the bare liquid \ liquid interface or an interface with a lipid monolayer suggest that the electron transfer follows that predicted by Marcus theory, with evidence for an inverted region. The SECM can also be used to probe processes at bilayer lipid membranes. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：7 / 17

页数：11

共 49 条

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[2]

[Anonymous], 1995, PHYS ELECTROCHEMISTR

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