Phosphorus-doped porous graphene nanosheet as metal-free electrocatalyst for triiodide reduction reaction in dye-sensitized solar cell

被引：42
|
作者：
Xu, Xiuwen [1 ]
Yang, Wang [1 ]
Chen, Bing [1 ]
Zhou, Chen [1 ]
Ma, Xinlong [1 ]
Hou, Liqiang [1 ]
Tang, Yushu [1 ]
Yang, Fan [1 ]
Ning, Guoqing [1 ]
Zhang, Liqiang [2 ]
Li, Yongfeng [1 ]
机构：
[1] China Univ Petr, Coll Chem Engn, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
[2] China Univ Petr, Coll Sci, Beijing 102249, Peoples R China
来源：
APPLIED SURFACE SCIENCE | 2017年 / 405卷
基金：
中国国家自然科学基金;
关键词：
Phosphorus doping; Porous graphene nanosheet; Electrocatalyst; Counter electrode; Dye-sensitized solar cells; COUNTER-ELECTRODE MATERIALS; CHEMICAL-VAPOR-DEPOSITION; HIGH-EFFICIENCY; OXYGEN REDUCTION; CARBON; NITROGEN; OXIDE; ARRAYS; BORON;
D O I：
10.1016/j.apsusc.2017.02.074
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Phosphorus-doped porous graphene nanosheet with a large specific surface area (1627.8 m(2) g(-1)) was prepared via chemical vapour deposition (CVD) with porous Mg-3(PO4)(2) as phosphorus (P) source and template, then it was applied as the counter electrode (CE) for dye-sensitized solar cell (DSSC). Due to the enhanced intrinsic catalytic activity induced by P doping, along with abundant open edge sites originated from the unique porous nanosheet, DSSCs with P doped porous graphene nanosheets CEs exhibited a high power conversion efficiency of 7.08%, which was comparable to that of DSSCs with Pt CEs. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：308 / 315
页数：8
相关论文
共 50 条
  • [1] Hierarchical porous carbons as a metal-free electrocatalyst of triiodide reduction for dye-sensitized solar cells
    Shao, Leng-Leng
    Chen, Ming
    Yuan, Zhong-Yong
    JOURNAL OF POWER SOURCES, 2014, 272 : 1091 - 1099
  • [2] Phosphorus-doped reduced graphene oxide as an electrocatalyst counter electrode in dye-sensitized solar cells
    Wang, Zegao
    Li, Pingjian
    Chen, Yuanfu
    He, Jiarui
    Liu, Jingbo
    Zhang, Wanli
    Li, Yanrong
    JOURNAL OF POWER SOURCES, 2014, 263 : 246 - 251
  • [3] Nitrogen and phosphorus dual-doped graphene as a metal-free high-efficiency electrocatalyst for triiodide reduction
    Yu, Chang
    Liu, Zhiqiang
    Meng, Xiangtong
    Lu, Bing
    Cui, Dan
    Qiu, Jieshan
    NANOSCALE, 2016, 8 (40) : 17458 - 17464
  • [4] Interconnected nitrogen and sulfur dual-doped porous carbon as efficient electrocatalyst for triiodide reduction in dye-sensitized solar cells
    Li, Zhao
    Yang, Wang
    Xu, Xiuwen
    Tang, Yushu
    Zeng, Ziwei
    Yang, Fan
    Zhang, Liqiang
    Ning, Guoqing
    Xu, Chunming
    Li, Yongfeng
    JOURNAL OF POWER SOURCES, 2016, 327 : 289 - 296
  • [5] Insight into the topological defects and dopants in metal-free holey graphene for triiodide reduction in dye-sensitized solar cells
    Yang, Wang
    Xu, Xiuwen
    Hou, Liqiang
    Ma, Xinlong
    Yang, Fan
    Wang, Ying
    Li, Yongfeng
    JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (12) : 5952 - 5960
  • [6] Phosphorus-doped hierarchical porous carbon as efficient metal-free electrocatalysts for oxygen reduction reaction
    Wu, Jiao
    Yang, Ruizhi
    Yan, Wenning
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (26) : 12941 - 12951
  • [7] Nitrogen-Doped Graphene Foams as Metal-Free Counter Electrodes in High-Performance Dye-Sensitized Solar Cells
    Xue, Yuhua
    Liu, Jun
    Chen, Hao
    Wang, Ruigang
    Li, Dingqiang
    Qu, Jia
    Dai, Liming
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (48) : 12124 - 12127
  • [8] Edge-selectively phosphorus-doped few-layer graphene as an efficient metal-free electrocatalyst for the oxygen evolution reaction
    Xiao, Zhaohui
    Huang, Xiaobing
    Xu, Lei
    Yan, Dafeng
    Huo, Jia
    Wang, Shuangyin
    CHEMICAL COMMUNICATIONS, 2016, 52 (88) : 13008 - 13011
  • [9] Phosphorus-doped graphene nanosheets as efficient metal-free oxygen reduction electrocatalysts
    Li, Rong
    Wei, Zidong
    Gou, Xinglong
    Xu, Wei
    RSC ADVANCES, 2013, 3 (25): : 9978 - 9984
  • [10] Sulfur-doped porous graphene frameworks as an efficient metal-free electrocatalyst for oxygen reduction reaction
    Wang, Chunxia
    Yang, Fan
    Xu, Chong
    Cao, Yan
    Zhong, Huangliang
    Li, Yongfeng
    MATERIALS LETTERS, 2018, 214 : 209 - 212
12345