Foam extrusion of polystyrene blown with HFC-134a

There is much interest in developing industrial processes to manufacture extruded polystyrene foam that do not involve ozone depleting blowing agents. A popular alternate candidate is HFC-134a. It has a zero ozone depletion factor and is nearer in chemical structure to standard blowing agents (CFC-22 and HCFC-142b) than carbon dioxide. Although exhibiting main good features, HFC-134a is not used widely as a blowing agent as low foam density is not readily achieved and extruder operation is difficult. A review of past and on-going works on the use of HFC-134 will be addressed first. Then attention will be paid mainly on some processing aspects, with emphasis on the plasticization behavior of polystyrene (PS) by HFC-134a and the effect of screw design on dynamic dissolution of HFC-134a in PS during foam extrusion. Solubility efficiency during extrusion processing has been assessed for different screw configurations by an in-line ultrasonic technique. These results have also been correlated to off-line solubility and diffusivity properties.