A one-pot reaction for biorefinery: combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides

被引：304

作者：

Takagaki, Atsushi ^{[1
]}

Ohara, Mika ^{[1
]}

Nishimura, Shun ^{[1
]}

Ebitani, Kohki ^{[1
]}

机构：

[1] JAIST, Sch Mat Sci, Kanazawa, Ishikawa 9231292, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 41期

关键词：

STAR POLYMERS; D-FRUCTOSE; BIOMASS; DEHYDRATION; FUELS; CONVERSION; CELLULOSE; GLUCOSE; 5-HYDROXYMETHYL-2-FURALDEHYDE; TRANSFORMATION;

D O I：

10.1039/b914087e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5-Hydroxymethylfurfural (HMF), one of the most important intermediates derived from biomass, was directly produced from monosaccharides (fructose and glucose) and disaccharides (sucrose and cellobiose) by a simple one-pot reaction including hydrolysis, isomerization and dehydration using solid acid and base catalysts under mild conditions.

引用

页码：6276 / 6278

页数：3

共 45 条

[1] Origins, current status, and future challenges of green chemistry [J].

Anastas, PT ;

Kirchhoff, MM .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694

[2] Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals [J].

Binder, Joseph B. ;

Raines, Ronald T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1979-1985

[3] Selective saccharides dehydration to 5-hydroxymethyl-2-furaldehyde by heterogeneous niobium catalysts [J].

Carlini, C ;

Giuttari, M ;

Galletti, AMR ;

Sbrana, G ;

Armaroli, T ;

Busca, G .

APPLIED CATALYSIS A-GENERAL, 1999, 183 (02) :295-302

[4] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[5] Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides [J].

Chheda, Juben N. ;

Roman-Leshkov, Yuriy ;

Dumesic, James A. .

GREEN CHEMISTRY, 2007, 9 (04) :342-350

[6] One-pot multi-component asymmetric cascade reactions catalyzed by soluble star polymers with highly branched non-interpenetrating catalytic cores [J].

Chi, Yonggui ;

Scroggins, Steven T. ;

Frechet, Jean M. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6322-+

[7] Green Chemistry: challenges and opportunities [J].

Clark, JH .

GREEN CHEMISTRY, 1999, 1 (01) :1-8

[8] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

[9] Chemicals from biomass [J].

Dodds, David R. ;

Gross, Richard A. .

SCIENCE, 2007, 318 (5854) :1250-1251

[10] Catalytic conversion of cellulose into sugar alcohols [J].

Fukuoka, Atsushi ;

Dhepe, Paresh L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (31) :5161-5163

← 1 2 3 4 5 →