Valence Band Offset at MoO3/CdTe Interface Probed by X-ray Photoelectron Spectroscopy

被引:0
作者
Paudel, N. R. [1 ]
Yan, Y.
机构
[1] Univ Toledo, Dept Phys & Astron, Toledo, OH 43606 USA
来源
2014 IEEE 40TH PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC) | 2014年
关键词
CdTe; VBO; MoO3; Cu-free; back contact; solar cells; XPS; TELLURIDE;
D O I
暂无
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
CdTe-based thin-film solar cells fabricated with Cufree MoO3/Au back contacts have achieved cell efficiencies as high as 14%. The incorporation of MoO3 buffer layers improves the open circuit voltage but reduces the fill factor (FF) of the CdTe cells compared to the cells using Au-only contacts. X-ray photoelectron spectroscopy measurements suggest a 2.75+/-0.20 eV valence band offset (VBO) between CdTe and MoO3. Such a large VBO explains the decrease in FF with the increase of the thickness of the MoO3 buffer layer.
引用
收藏
页码:2397 / 2399
页数:3
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