Aryldiplatinum(II) complexes containing dimethyl sulfide and bis(diphenylphosphino) methane as bridging ligands

被引:29
|
作者
Rashidi, M [1 ]
Hashemi, M
Khorasani-Motlagh, M
Puddephatt, RJ
机构
[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 71454, Iran
[2] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
关键词
D O I
10.1021/om990784t
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A versatile and yet simple approach to synthesize a series of uncommon symmetrical and unsymmetrical diplatinum(II) complexes cis, cis-[Ar2Pt(mu-SMe2)(mu-dppm)PtAr'(2)], 3, in which Ar or Ar' = Ph, p-MeC6H4, m-MeC6H4, orp-MeOC6H4, has been developed by the reaction of either cis-[PtAr2(SMe2)(2)], 1, with [PtAr'(2)(dppm)], 2, or cis-[PtAr'(2)(SMe2)(2)] with [PtAr2(dppm)].
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页码:2751 / 2755
页数:5
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