Development of Active and Stable Low Nickel Content Catalysts for Dry Reforming of Methane

被引：53

作者：

Quan Luu Manh Ha ^{[1
,2
]}

Armbruster, Udo ^{[1
]}

Atia, Hanan ^{[1
]}

Schneider, Matthias ^{[1
]}

Lund, Henrik ^{[1
]}

Agostini, Giovanni ^{[1
]}

Radnik, Joerg ^{[3
]}

Huyen Thanh Vuong ^{[1
]}

Martin, Andreas ^{[1
]}

机构：

[1] Leibniz Inst Katalyse eV, Dept Heterogeneous Catalyt Proc, Albert Einstein Str 29a, D-18059 Rostock, Germany

[2] Vietnam Petr Inst, 167 Trung Kinh, Hanoi 100000, Vietnam

[3] Fed Inst Mat Res & Testing, Div 6 1, Surface Anal & Interfacial Chem, Richard Willstatter Str 12, D-12489 Berlin, Germany

来源：

CATALYSTS | 2017年 / 7卷 / 05期

关键词：

dry reforming of methane; carbon dioxide; nickel; MgO-Al2O3 solid solution; NI-BASED CATALYSTS; PARTIAL OXIDATION; CARBON-DIOXIDE; CALCINATION TEMPERATURE; SUPPORTED CATALYSTS; HYDROGEN-PRODUCTION; SOLID-SOLUTIONS; SYNTHESIS GAS; CO2; MGO;

D O I：

10.3390/catal7050157

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Methane dry reforming (DRM) was investigated over highly active Ni catalysts with low metal content (2.5wt%) supported on Mg-Al mixed oxide. The aim was to minimize carbon deposition and metal sites agglomeration on the working catalyst which are known to cause catalyst deactivation. The solids were characterized using N-2 adsorption, X-ray diffraction, temperature-programmed reduction, X-ray photoelectron spectroscopy, and UV-Vis diffuse reflectance spectroscopy. The results showed that MgO-Al2O3 solid solution phases are obtained when calcining Mg-Al hydrotalcite precursor in the temperature range of 550-800 degrees C. Such phases contribute to the high activity of catalysts with low Ni content even at low temperature (500 degrees C). Modifying the catalyst preparation with citric acid significantly slows the coking rate and reduces the size of large octahedrally coordinated NiO-like domains, which may easily agglomerate on the surface during DRM. The most effective Ni catalyst shows a stable DRM course over 60 h at high weight hourly space velocity with very low coke deposition. This is a promising result for considering such catalyst systems for further development of an industrial DRM technology.

引用

页数：17

共 55 条

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