Abatement and toxicity reduction of antimicrobials by UV/H2O2 process

被引:17
作者
Urbano, Vanessa Ribeiro [1 ]
Peres, Marcela Souza [1 ]
Maniero, Milena Guedes [1 ]
Guimaraes, Jose Roberto [1 ]
机构
[1] Univ Estadual Campinas, Sch Civil Engn Architecture & Urban Design, POB 6143, BR-13083889 Campinas, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Advanced oxidation process; Antimicrobial activity; Ofloxacin; Peroxidation; Photolysis; Sulfaquinoxaline; PHOTO-FENTON; WASTE-WATER; SPECTROPHOTOMETRIC DETERMINATION; QUINOLONE ANTIBACTERIALS; EMERGING CONTAMINANTS; DEGRADATION; OFLOXACIN; PHARMACEUTICALS; ANTIBIOTICS; REMOVAL;
D O I
10.1016/j.jenvman.2017.02.028
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Antimicrobials are continuously detected in environmental waters and their removal is important to avoid health and microorganisms damage. In this work, the peroxidation assisted by ultraviolet radiation (UV/H2O2) was studied to verify if the process was able to degrade sulfaquinoxaline and ofloxacin antimicrobials and to remove the toxicity and the antimicrobial activity of the solution. This process was effective on degradation of the antimicrobials, despite the antimicrobial activity removal, the toxicity of the solution increased throughout the reaction time. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:439 / 447
页数:9
相关论文
共 48 条
[1]   Estimation of kinetic parameters and UV doses necessary to remove twenty-three pharmaceuticals from pre-treated urban wastewater by UV/H2O2 [J].
Afonso-Olivares, C. ;
Fernandez-Rodriguez, C. ;
Ojeda-Gonzalez, R. J. ;
Sosa-Ferrera, Z. ;
Santana-Rodriguez, J. J. ;
Dona Rodriguez, J. M. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2016, 329 :130-138
[2]   Engineering the specificity of antibacterial fluoroquinolones:: Benzenesulfonamide modifications at C-7 of ciprofloxacin change its primary target in Streptococcus pneumoniae from topoisomerase IV to gyrase [J].
Alovero, FL ;
Pan, XS ;
Morris, JE ;
Manzo, RH ;
Fisher, LM .
ANTIMICROBIAL AGENTS AND CHEMOTHERAPY, 2000, 44 (02) :320-325
[3]  
[Anonymous], ENV SCI POLLUT RES
[4]  
[Anonymous], 2012, 154113 ABNT NBR
[5]   Protonation equilibria of quinolone antibacterials in acetonitrile-water mobile phases used in LC [J].
Barbosa, J ;
Berges, R ;
Toro, I ;
SanzNebot, V .
TALANTA, 1997, 44 (07) :1271-1283
[6]   Photochemical degradation of sulfadiazine, sulfamerazine and sulfamethazine: Relevance of concentration and heterocyclic aromatic groups to degradation kinetics [J].
Batista, Ana Paula S. ;
Pires, Flavio Chiquetto C. ;
Teixeira, Antonio Carlos S. C. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2014, 286 :40-46
[7]   Solar photocatalysis as a tertiary treatment to remove emerging pollutants from wastewater treatment plant effluents [J].
Bernabeu, A. ;
Vercher, R. F. ;
Santos-Juanes, L. ;
Simon, P. J. ;
Lardin, C. ;
Martinez, M. A. ;
Vicente, J. A. ;
Gonzalez, R. ;
Llosa, C. ;
Arques, A. ;
Amat, A. M. .
CATALYSIS TODAY, 2011, 161 (01) :235-240
[8]   Occurrence and behavior of antibiotics in water and sediments from the Huangpu River, Shanghai, China [J].
Chen, K. ;
Zhou, J. L. .
CHEMOSPHERE, 2014, 95 :604-612
[9]  
da Silva CR, 2011, J ADV OXID TECHNOL, V14, P106
[10]   Degradation of 32 emergent contaminants by UV and neutral photo-fenton in domestic wastewater effluent previously treated by activated sludge [J].
De la Cruz, N. ;
Gimenez, J. ;
Esplugas, S. ;
Grandjean, D. ;
de Alencastro, L. F. ;
Pulgarin, C. .
WATER RESEARCH, 2012, 46 (06) :1947-1957