Platinum complexes featuring terminally bound Ga+ and In+ ions

被引：19
作者：
Aldridge, Simon [1 ]
机构：
[1] Cardiff Univ, Sch Chem, Ctr Fundamental & Appl Main Grp Chem, Cardiff CF10 3AT, Wales
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期
关键词：
cations; gallium; indium; Lewis acids; subvalent ligands;
D O I：
10.1002/anie.200603643
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Alone at the apex: The first metal complexes with Ga+ or In+ cations as terminally bound ligands have recently been synthesized. Structural and computational studies suggest a Lewis acid/base Pt-Ga interaction for [GaPt(GaCp*)4]+ (1; Pt blue, Ga violet, C gray; ArF = C6H3-(CF 3)2-3,5). The Group 13 cation therefore functions as an acceptor ligand, with significant components of both σ and π symmetry contributing to the Pt-Ga linkage. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：8097 / 8099
页数：3
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