Optimization of biodiesel production from waste cooking oil using ion-exchange resins

被引：7

作者：

Kolyaei, Maryam ^{[1
]}

Zahedi, Gholamreza ^{[2
]}

Nasef, Mohamed Mahmoud ^{[2
]}

Azarpour, Abbas ^{[1
]}

机构：

[1] Univ Teknol Malaysia, Fac Chem Engn, Dept Chem Engn, Johor Baharu, Johor, Malaysia

[2] Ozone Solut Inc, Hull, IA 51250 USA

来源：

INTERNATIONAL JOURNAL OF GREEN ENERGY | 2016年 / 13卷 / 01期

关键词：

Optimization; esterification; reaction; ion exchange resins; FREE FATTY-ACIDS; ESTERIFICATION; FUEL;

D O I：

10.1080/15435075.2014.909354

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Waste cooking oil is a potential substitution of refined vegetable oil for the production of biodiesel due to the low cost of raw material and for solving their disposal problem. In this study, optimization of esterification process of free fatty acids in artificially acidified soybean oil with oleic acid has been carried out using methanol as an agent and ion exchange resin as a heterogeneous catalyst. The esterification reaction has been investigated based on the mass balance of the developed model. The model has been validated against experimental data and effects of temperature and catalyst weight have been analyzed. Thereafter, optimization process has been fulfilled for two different objective functions as conversion of acid oil and benefit. Optimization results indicated that the maximum conversion of acid is 95.95%, which is achievable at 4.48-g catalyst loading and reaction temperature of 120 degrees C. Maximum benefit was obtained as US$0.057 per batch of reaction at a catalyst amount of 1 g and temperature of 120 degrees C.

引用

页码：28 / 33

页数：6

共 26 条

[1]

Aesar Alfa, 2010, ION EXCHANGE RESIN

[2] Synthesis of Ferric-Manganese Doped Tungstated Zirconia Nanoparticles as Heterogeneous Solid Superacid Catalyst for Biodiesel Production From Waste Cooking Oil [J].

Alhassan, Fatah H. ;

Rashid, Umer ;

Yunus, Robiah ;

Sirat, Kamaliah ;

Lokman, Ibrahim M. ;

Taufiq-Yap, Yun Hin .

INTERNATIONAL JOURNAL OF GREEN ENERGY, 2015, 12 (09) :987-994

[3] EFFECT OF FREE FATTY ACIDS AND SHORT CHAIN ALCOHOLS ON CONVERSION OF WASTE COOKING OIL TO BIODIESEL [J].

Awad, S. ;

Paraschiv, M. ;

Geo, V. Edwin ;

Tazerout, M. .

INTERNATIONAL JOURNAL OF GREEN ENERGY, 2014, 11 (05) :441-453

[4] A kinetic study of the esterification of free fatty acids (FFA) in sunflower oil [J].

Berrios, M. ;

Siles, J. ;

Martin, M. A. ;

Martin, A. .

FUEL, 2007, 86 (15) :2383-2388

[5] The Kinetics of Interesterfication on Waste Cooking Oil (Sunflower Oil) for the Production of Fatty Acid Alkyl Esters using a Whole Cell Biocatalyst (Rhizopus oryzae) and Pure Lipase Enzyme [J].

Bharathiraja, B. ;

Jayamuthunagai, J. ;

Praveenkumar, R. ;

Jayakumar, M. ;

Palani, S. .

INTERNATIONAL JOURNAL OF GREEN ENERGY, 2015, 12 (10) :1012-1017

[6] A comparative study of the production of ethyl esters from vegetable oils as a biodiesel fuel optimization by factorial design [J].

Bouaid, Abderrahim ;

Martinez, Mercedes ;

Aracil, Jose .

CHEMICAL ENGINEERING JOURNAL, 2007, 134 (1-3) :93-99

[7] Integrated environmental assessment of biodiesel production from soybean in Brazil [J].

Cavalett, Otavio ;

Ortega, Enrique .

JOURNAL OF CLEANER PRODUCTION, 2010, 18 (01) :55-70

[8] Biodiesel production using cation-exchange resin as heterogeneous catalyst [J].

Feng, Yaohui ;

He, Benqiao ;

Cao, Yuhe ;

Li, Jianxin ;

Liu, Meng ;

Yan, Feng ;

Liang, Xiaoping .

BIORESOURCE TECHNOLOGY, 2010, 101 (05) :1518-1521

[9] Optimisation of FAME production from waste cooking oil for biodiesel use [J].

Fernando Bautista, Luis ;

Vicente, Gemma ;

Rodriguez, Rosalia ;

Pacheco, Maria .

BIOMASS & BIOENERGY, 2009, 33 (05) :862-872

[10]

Good Energy, 2010, CARS OK BIOD

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