Hydrothermal Syntheses and Crystal Structures of Cd(II) and Zn(II) Complexes Constructed with 1,4-Benzenedicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands

被引：4
|
作者：
Che Guang-Bo [1 ]
Li Wei-Wei [2 ]
Wang Shan-Shan [2 ]
Wang Dan [3 ]
Zhao Han [2 ]
Liu Chun-Bo [1 ,2 ]
机构：
[1] Jilin Normal Univ, Chinese Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Siping 136000, Jilin, Peoples R China
[2] Jilin Normal Univ, Coll Chem, Siping 136000, Jilin, Peoples R China
[3] S China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 10期
关键词：
cadmium(II) complex; zinc(II) complex; 1,4-benzenedicarboxylic acid; imidazo[4,5-f][1,10]phenanthroline; crystal structure;
D O I：
10.3969/j.issn.1001-4861.2013.00.337
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel metal-organic frameworks (MOFs), [Cd(bdc)(Imphen)(H2O)](n)center dot nH(2)O (1) and [Zn(bdc)(Imphen)(H2O)](n)center dot nH(2)O (2) based on 1,4-benzenedicarboxylic acid (H(2)bdc) and imidazo[4,5-f][1,10]phenanthroline (Imphen) ligands, have been constructed under hydrothermal conditions. The complexes are characterized by elemental analyse, single crystal X-ray diffraction. Structural analyses show that the complexes 1 and 2 all present one dimensional chain and bdc(2-) ligands display different coordination modes. Furthermore, the adjacent chains are further connected by the hydrogen-bonding and pi-pi stacking interactions generating three-dimensional supramolecular structures. In addition, thermal stability and luminescent properties of two complexes were also investigated. CCDC: 947287, 1; 947288, 2.
引用
收藏
页码：2188 / 2194
页数：7
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