Gold- and silver-catalyzed allylic alkylation of 1,3-dicarbonyl compounds with allylic alcohols

被引：41

作者：

Kothandaraman, Prasath ^{[1
]}

Rao, Weidong ^{[1
]}

Zhang, Xiaoxiang ^{[1
]}

Chan, Philip Wai Hong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

TETRAHEDRON | 2009年 / 65卷 / 09期

关键词：

ACTIVE METHYLENE-COMPOUNDS; NUCLEOPHILIC-SUBSTITUTION; DIRECT AMINATION; PART; C-C; ALLYLATION; SULFONAMIDES; BENZYLATION; ACTIVATION;

D O I：

10.1016/j.tet.2008.11.102

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly efficient gold- and silver-catalyzed allylic alkylation of 1,3-dicarbonyl compounds with allylic alcohols has been developed. The reaction was shown to proceed expediently for a wide variety of 1,3-dicarbonyl compounds and allylic alcohols, including 1 degrees and terminal ones, under very mild conditions at room temperature in good to excellent yields (55-96%). (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1833 / 1838

页数：6

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