Strong stretching theory for diblock copolymers in thin films

被引:8
|
作者
Heckmann, Marianne [1 ]
Drossel, Barbara [1 ]
机构
[1] Tech Univ Darmstadt, Inst Festkorperphys, D-64289 Darmstadt, Germany
来源
JOURNAL OF CHEMICAL PHYSICS | 2008年 / 129卷 / 21期
关键词
density functional theory; free energy; phase diagrams; polymer blends; polymer films; SCF calculations;
D O I
10.1063/1.3027437
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the microphases of diblock copolymers confined to thin films in the strong segregation limit. We evaluate the free energies of the possible phases and present phase diagrams for block copolymers with a cylindrical bulk phase in dependence of the film thickness and the walls' preference for one of the monomers. We find four stable types of phases, which were also found in studies based on self-consistent field theory and dynamic density functional theory. We argue that perforated lamellas are not a stable phase.
引用
收藏
页数:10
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