Synthesis of Y3Fe5O12 via Thermal Decomposition of Polynuclear Coordination Compounds

被引:0
作者
Patron, L. [1 ]
Carp, O. [1 ]
Mindru, I. [1 ]
Marinescu, G. [1 ]
Diamandescu, L. [2 ]
Reller, A. [3 ]
机构
[1] Inst Phys Chem, Splaiul Independentei 202, Bucharest 060021, Romania
[2] Inst Atom Phys, Natl Inst Mat Phy, POB Mg-6, R-76900 Bucharest, Romania
[3] Univ Augsburg, Solid State Chem, D-86159 Augsburg, Germany
来源
ADVANCED MATERIALS FORUM IV | 2008年 / 587-588卷
关键词
iron garnet; polynuclear coordination precursor;
D O I
10.4028/www.scientific.net/MSF.587-588.278
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The possibility of obtaining yttrium iron garnet (Y3Fe5O12, YIG) through thermal decomposition of two coordination compounds with malate and gluconate anions as ligands. (NH4)(6)[Y-3(C4O5H4)(6)(C4O5H3)(6)]center dot 12H(2)O and (NH4)(6)[Y3Fe5(C6O7H10)(6)(C6O7H9)(6)]center dot 8H(2)O. A mixture of simple oxides, namely Y2O3 and alpha-Fe2O3, orthorhombic ferrite YFeO3 and small amounts Y3Fe5O12, is generated from the thermolysis of malate compound. while a clean Y3Fe5O12 is obtained from gluconate compound.
引用
收藏
页码:278 / +
页数:3
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