Iron complexes of tris(4-nitrophenyl)corrole, with emphasis on the (nitrosyl)iron complex

被引：24

作者：

Singh, Pinky ^{[1
]}

Saltsman, Irena ^{[1
]}

Mahammed, Atif ^{[1
]}

Goldberg, Israel ^{[2
]}

Tumanskii, Boris ^{[1
]}

Gross, Zeev ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Schulich Fac Chem, IL-32000 Haifa, Israel

[2] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2012年 / 16卷 / 5-6期

基金：

以色列科学基金会;

关键词：

corroles; synthesis; iron; N-15-; Fe-57-labeled corroles; NMR; electrochemistry; EPR; TRANSITION-METAL CENTERS; STRUCTURAL-CHARACTERIZATION; NONINNOCENT LIGANDS; SPIN DELOCALIZATION; IRON(III) CORROLES; RHODIUM COMPLEXES; RESONANCE RAMAN; METALLOCORROLES; SPECTROSCOPY; ELECTROCHEMISTRY;

D O I：

10.1142/S1088424612500605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The iron complexes of 5,10,15-tris(4-nitrophenyl)corrole have been prepared and characterized by various spectroscopic techniques. The (nitrosyl) iron complex is diamagnetic and its X-ray structure reveals an almost perfectly linear Fe-N-O bond. EPR spectroscopy in conjunction with N-15 labelling were used to deduce the redox centre of the one-electron reduction and oxidation products of the (nitrosyl)iron corrole.

引用

页码：663 / 673

页数：11

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