Indirectly detected heteronuclear correlation solid-state NMR spectroscopy of naturally abundant 15N nuclei

被引：52

作者：

Althaus, Stacey M. ^{[1
,2
]}

Mao, Kanmi ^{[1
,2
]}

Stringer, John A. ^{[3
]}

Kobayashi, Takeshi ^{[2
]}

Pruski, Marek ^{[1
,2
]}

机构：

[1] US DOE, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[3] Agilent Technol, Loveland, CO 80537 USA

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 2014年 / 57-58卷

关键词：

Solid-state N-15 NMR; FastMAS; J-coupling; HETCOR; INEPT; Indirect detection; Mesoporous silica; INVERSE DETECTION; CHEMICAL-SHIFT; FAST-MAS; SENSITIVITY ENHANCEMENT; CROSS-POLARIZATION; H-1; RESOLUTION; PROTON; PEPTIDE; MAGNITUDES;

D O I：

10.1016/j.ssnmr.2013.11.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two-dimensional indirectly detected through-space and through-bond H-1{N-15} solid-state NMR experiments utilizing fast magic angle spinning (MAS) and homonuclear multipulse H-1 decoupling are evaluated. Remarkable efficiency of polarization transfer can be achieve data MAS rate of 40kHz by both cross-polarization and INEPT, which makes these methods applicable for routine characterizations of natural abundance solids. The first measurement of 2D H-1{N-15} HETCOR spectrum of natural abundance surface species is also reported. (C) 2013 Elsevier Inc. All rights reserved.

引用

页码：17 / 21

页数：5

共 54 条

[1] Mufti-scale NMR characterisation of mesostructured materials using 1H→13C through-bond polarisation transfer, fast MAS, and 1H spin diffusion [J].

Alonso, B ;

Massiot, D .

JOURNAL OF MAGNETIC RESONANCE, 2003, 163 (02) :347-352

[2] Solid-State NMR Studies of Fossil Fuels using One- and Two-Dimensional Methods at High Magnetic Field [J].

Althaus, Stacey M. ;

Mao, Kanmi ;

Kennedy, Gordon J. ;

Pruski, Marek .

ENERGY & FUELS, 2012, 26 (07) :4405-4412

[3] SIMPSON: A general simulation program for solid-state NMR spectroscopy [J].

Bak, M ;

Rasmussen, JT ;

Nielsen, NC .

JOURNAL OF MAGNETIC RESONANCE, 2000, 147 (02) :296-330

[4] CORRELATION OF PROTON AND N-15 CHEMICAL-SHIFTS BY MULTIPLE QUANTUM NMR [J].

BAX, A ;

GRIFFEY, RH ;

HAWKINS, BL .

JOURNAL OF MAGNETIC RESONANCE, 1983, 55 (02) :301-315

[5] NATURAL ABUNDANCE N-15 NMR BY ENHANCED HETERONUCLEAR SPECTROSCOPY [J].

BODENHAUSEN, G ;

RUBEN, DJ .

CHEMICAL PHYSICS LETTERS, 1980, 69 (01) :185-189

[6] An investigation of the hydrogen-bonding structure in bilirubin by 1H double-quantum magic-angle spinning solid-state NMR spectroscopy [J].

Brown, SP ;

Zhu, XX ;

Saalwächter, K ;

Spiess, HW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (18) :4275-4285

[7] Indirect detection of nitrogen-14 in solids via protons by nuclear magnetic resonance spectroscopy [J].

Cavadini, Simone ;

Antonijevic, Sasa ;

Lupulescu, Adonis ;

Bodenhausen, Geoffrey .

JOURNAL OF MAGNETIC RESONANCE, 2006, 182 (01) :168-172

[8] Nitrogen-14 NMR spectroscopy using residual dipolar splittings in solids [J].

Cavadini, Simone ;

Lupulescu, Adonis ;

Antonijevic, Sasa ;

Bodenhausen, Geoffrey .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (24) :7706-7707

[9] Urea and Thiourea-Functionalized Mesoporous Silica Nanoparticle Catalysts with Enhanced Catalytic Activity for Diels-Alder Reaction [J].

Chen, Hung-Ting ;

Trewyn, Brian G. ;

Wiench, Jerzy W. ;

Pruski, Marek ;

Lin, Victor S. -Y. .

TOPICS IN CATALYSIS, 2010, 53 (3-4) :187-191

[10] Ultrahigh resolution in proton solid-state NMR spectroscopy at high levels of deuteration [J].

Chevelkov, V ;

Rehbein, K ;

Diehl, A ;

Reif, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) :3878-3881

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