Synthesis, Characterization, and Molluscicidal Activity of Mn, Co, Ni, and Cu Complexes of Ethyl 5-Amino-2-(Methylthio) Thiazole-4-Carboxylate

被引:10
作者
El-Bayouki, Khairy A. M. [1 ]
Basyouni, Wahid M. [1 ]
Mostafa, Eslam A. [1 ]
Abbas, Samir Y. [1 ]
机构
[1] Natl Res Ctr, Organometall & Organometalloid Chem Dept, Cairo 11111, Egypt
关键词
5-amino-thiazole-4-carboxylate; metal complexes; molluscicidal activity; TRANSITION-METAL COMPLEXES; BIOLOGICAL-ACTIVITY; CRYSTAL-STRUCTURE; DERIVATIVES; THIOSEMICARBAZONES; CHEMISTRY; PEPTIDE; IONS;
D O I
10.1080/15533174.2013.763274
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The Mn, Co, Ni, and Cu complexes of ethyl 5-amino-2-(methy lthio) thiazole-4-carboxylate were synthesized. The structure of the metal complexes was established by microanalyses, IR, and UV-vis spectra. Thermal and electron spin resonance properties of the metal complexes were studied by TGA and ESR techniques. Metal complexes analyses suggested that: the ligand coordinated to the metal ions via nitrogen of amino group and the oxygen of carbonyl group; the synthesized complexes are binuclear with four-coordinated metal centers. Moreover, octahedral structure is suggested for all complexes. Molluscicidal activity of metal complexes was tested against Biomphalaria alexandrina snails.
引用
收藏
页码:537 / 540
页数:4
相关论文
共 31 条
[1]   Coordination chemistry of thiazoline/thiazolidine derivatives.: I:: Crystal structure of 2-(2-pyridyl)imino-N-(2-thiazolin-2-yl)thiazolidine (PyTT) and study of its interaction with nickel(II) [J].
Bernalte-García, A ;
García-Barros, FJ ;
Higes-Rolando, FJ ;
Luna-Giles, F .
POLYHEDRON, 1999, 18 (22) :2907-2912
[2]  
Buristrov S. I., 1964, USSR Patent, Patent No. 154861
[3]   TRANSITION-METAL COMPLEXES OF THIOSEMICARBAZIDE AND THIOSEMICARBAZONES [J].
CAMPBELL, MJM .
COORDINATION CHEMISTRY REVIEWS, 1975, 15 (2-3) :279-319
[4]   SYNTHESIS AND BIOLOGICAL-ACTIVITY OF BENZOTHIAZOLO [3,2-A]QUINOLINIUM AND BENZOXAZOLO[3,2-A]QUINOLINIUM SALTS [J].
COX, O ;
JACKSON, H ;
VARGAS, VA ;
BAEZ, A ;
COLON, JI ;
GONZALEZ, BC ;
DELEON, M .
JOURNAL OF MEDICINAL CHEMISTRY, 1982, 25 (11) :1378-1381
[5]   Characterization and DNA-interaction studies of 1,1-dicyano-2,2-ethylene dithiolate Ni(II) mixed-ligand complexes with 2-amino-5-methyl thiazole, 2-amino-2-thiazoline and imidazole. Crystal structure of [Ni(i-MNT)(2a-5mt)2] [J].
Cox, Philip J. ;
Psomas, George ;
Bolos, Christos A. .
BIOORGANIC & MEDICINAL CHEMISTRY, 2009, 17 (16) :6054-6062
[6]   Spectroscopic characterization and biological activity of salicylaldehyde thiazolyl hydrazone ligands and their metal complexes [J].
Cukurovali, A ;
Yilmaz, I ;
Kirbag, S .
TRANSITION METAL CHEMISTRY, 2006, 31 (02) :207-213
[7]   Preparation and structural studies on metal complexes of some carboxamides [J].
Eid, AE .
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2001, 31 (06) :997-1009
[8]  
ELBAYOUKI KAM, 1991, AN QUIM-INT, V87, P899
[9]   NEW THIAZOLO[5,4-D]PYRIMIDINES WITH MOLLUSCICIDAL PROPERTIES [J].
ELBAYOUKI, KAM ;
BASYOUNI, WM .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (10) :3794-3796
[10]  
Emeleus H. J., 1965, ADV INORGANIC CHEM R, V7