Synthesis, Characterization, and Molluscicidal Activity of Mn, Co, Ni, and Cu Complexes of Ethyl 5-Amino-2-(Methylthio) Thiazole-4-Carboxylate

被引:10
作者
El-Bayouki, Khairy A. M. [1 ]
Basyouni, Wahid M. [1 ]
Mostafa, Eslam A. [1 ]
Abbas, Samir Y. [1 ]
机构
[1] Natl Res Ctr, Organometall & Organometalloid Chem Dept, Cairo 11111, Egypt
关键词
5-amino-thiazole-4-carboxylate; metal complexes; molluscicidal activity; TRANSITION-METAL COMPLEXES; BIOLOGICAL-ACTIVITY; CRYSTAL-STRUCTURE; DERIVATIVES; THIOSEMICARBAZONES; CHEMISTRY; PEPTIDE; IONS;
D O I
10.1080/15533174.2013.763274
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The Mn, Co, Ni, and Cu complexes of ethyl 5-amino-2-(methy lthio) thiazole-4-carboxylate were synthesized. The structure of the metal complexes was established by microanalyses, IR, and UV-vis spectra. Thermal and electron spin resonance properties of the metal complexes were studied by TGA and ESR techniques. Metal complexes analyses suggested that: the ligand coordinated to the metal ions via nitrogen of amino group and the oxygen of carbonyl group; the synthesized complexes are binuclear with four-coordinated metal centers. Moreover, octahedral structure is suggested for all complexes. Molluscicidal activity of metal complexes was tested against Biomphalaria alexandrina snails.
引用
收藏
页码:537 / 540
页数:4
相关论文
共 31 条