Structure and dynamics investigations of a partially hydrogenated graphene/Ni(111) surface

被引：19
|
作者：
Bahn, Emanuel [1 ,2 ]
Tamtoegl, Anton [2 ,3 ]
Ellis, John [2 ]
Allison, William [2 ]
Fouquet, Peter [1 ]
机构：
[1] Inst Laue Langevin, 71 Ave Martyrs, F-38042 Grenoble 9, France
[2] Cavendish Lab, 19 JJ Thomson Ave, Cambridge CB3 0HE, England
[3] Graz Univ Technol, Inst Expt Phys, Petersgasse 16, A-8010 Graz, Austria
来源：
CARBON | 2017年 / 114卷
基金：
英国工程与自然科学研究理事会; 奥地利科学基金会;
关键词：
Graphene; Ni(111); Hydrogenation; Helium atom scattering; ATOMIC-HYDROGEN; REVERSIBLE HYDROGENATION; EPITAXIAL GRAPHENE; MONOLAYERS; DIFFRACTION; TRANSITION; ADSORPTION; SCATTERING; DIFFUSION; EXPOSURE;
D O I：
10.1016/j.carbon.2016.12.055
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Using helium(-3) atom scattering, we have studied the adsorption kinetics, the structure and the diffusional dynamics of atomic hydrogen on the surface of a graphene monolayer on Ni(111). Diffraction measurements reveal a 4 degrees rotated rectangular hydrogen overstructure. Hydrogen adsorption and desorption exhibit activation barriers of E-a = (89 +/- 7) meV and E-d = (1.8 +/- 0.2) eV, respectively. Helium(-3) spin-echo measurements showed no decay of the spatial correlation function (or intermediate scattering function) within the time range of the spectrometer. Hence, we are able to set lower limits for a possible hydrogen surface diffusion rate. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：504 / 510
页数：7
相关论文
共 50 条
  • [21] Room temperature ferromagnetism in partially hydrogenated epitaxial graphene
    Xie, Lanfei
    Wang, Xiao
    Lu, Jiong
    Ni, Zhenhua
    Luo, Zhiqiang
    Mao, Hongying
    Wang, Rui
    Wang, Yingying
    Huang, Han
    Qi, Dongchen
    Liu, Rong
    Yu, Ting
    Shen, Zexiang
    Wu, Tom
    Peng, Haiyang
    Oezyilmaz, Barbaros
    Loh, Kianping
    Wee, Andrew T. S.
    Ariando
    Chen, Wei
    APPLIED PHYSICS LETTERS, 2011, 98 (19)
  • [22] Graphene monolayer rotation on Ni(111) facilitates bilayer graphene growth
    Dahal, Arjun
    Addou, Rafik
    Sutter, Peter
    Batzill, Matthias
    APPLIED PHYSICS LETTERS, 2012, 100 (24)
  • [23] Growth and electronic structure of nitrogen-doped graphene on Ni(111)
    Koch, R. J.
    Weser, M.
    Zhao, W.
    Vines, F.
    Gotterbarm, K.
    Kozlov, S. M.
    Hoefert, O.
    Ostler, M.
    Papp, C.
    Gebhardt, J.
    Steinrueck, H. -P.
    Goerling, A.
    Seyller, Th.
    PHYSICAL REVIEW B, 2012, 86 (07)
  • [24] The structure of NO on Ni(111) at low coverage
    Lindsay, R
    Theobald, A
    Giessel, T
    Schaff, O
    Bradshaw, AM
    Booth, NA
    Woodruff, DP
    SURFACE SCIENCE, 1998, 405 (2-3) : L566 - L572
  • [25] Segregation growth of epitaxial graphene overlayers on Ni(111)
    Yang, Yang
    Fu, Qiang
    Wei, Wei
    Bao, Xinhe
    SCIENCE BULLETIN, 2016, 61 (19) : 1536 - 1542
  • [26] Boudouard reaction under graphene cover on Ni(111)
    Davi, Rocco
    Carraro, Giovanni
    Stojkovska, Marija
    Smerieri, Marco
    Savio, Letizia
    Lewandowski, Mikolaj
    Gallet, Jean-Jacques
    Bournel, Fabrice
    Rocca, Mario
    Vattuone, Luca
    APPLIED SURFACE SCIENCE, 2022, 599
  • [27] Graphene on Ni(111): Electronic Corrugation and Dynamics from Helium Atom Scattering
    Tamtoegl, Anton
    Bahn, Emanuel
    Zhu, Jianding
    Fouquet, Peter
    Ellis, John
    Allison, William
    JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (46) : 25983 - 25990
  • [28] Structure and dynamics of fullerenes adsorbed on the Au(111) surface
    Guo, S
    Fogarty, D
    Nagel, P
    Kandel, SA
    PHYSICAL CHEMISTRY OF INTERFACES AND NANOMATERIALS III, 2004, 5513 : 185 - 195
  • [29] Scanning tunneling microscopic investigations for studying conformational change of underlying Cu(111) and Ni(111) during graphene growth
    Ahn, Jong-Guk
    Bang, Jiwon
    Jung, Jaehoon
    Kim, Yousoo
    Lim, Hyunseob
    SURFACE SCIENCE, 2020, 693
  • [30] Thermal rectification in partially hydrogenated graphene with grain boundary, a non-equilibrium molecular dynamics study
    Shavikloo, Masoumeh
    Kimiagar, Salimeh
    COMPUTATIONAL MATERIALS SCIENCE, 2017, 139 : 330 - 334
12345