The properties including extraction time to reach equilibrium, extraction amount, selectivity, detection limits, linear range, thermal stability and the life of coatings, for the new-coated fiber containing C-60 have been investigated comprehensively. Compared to non-polar polydimethylsiloxane (PDMS) commercial availably, the C-60 fibers are more efficient, selective and sensitive for aromatic compounds. The thermal stability, reproducibility and lifetime of polysilicone fullerence (PF) coat are better than the similar polarity of PDMS commercial availably.