Study on the Crystallization Kinetics of Polymer Thin Films

被引:1
作者
Ren, Yijin [1 ]
机构
[1] Hubei Univ Automot Technol, Dept Mat Engn, Shiyan 442002, Hubei, Peoples R China
来源
INTELLIGENT SYSTEM AND APPLIED MATERIAL, PTS 1 AND 2 | 2012年 / 466-467卷
关键词
Polymer thin film; Crystallization kinetics; Film thickness; ULTRATHIN POLY(DI-N-HEXYLSILANE) FILMS; CRYSTAL-GROWTH; POLY(ETHYLENE OXIDES); OXIDIZED SILICON; IN-SITU;
D O I
10.4028/www.scientific.net/AMR.466-467.102
中图分类号
TP18 [人工智能理论];
学科分类号
081104 ; 0812 ; 0835 ; 1405 ;
摘要
The crystallization kinetics of polymer thin film has a great difference from that in the bulk. Generally, the growth rate of the crystal confined in thin film reduces with decreasing film thickness, which is believed that the interaction between chains and substrate is responsible for the decrease of the growth rate. In addition, the ratio of film thickness over crystal thickness is also a key parameter in determining the growth rate. The relationship between the crystal lateral size and the crystallization time also dominates the crystal growth mechanism in polymer thin film.
引用
收藏
页码:102 / 105
页数:4
相关论文
共 50 条
[31]   Geometrical effects during crystallization under confinement in electrospun core-shell fibers. DSC study of crystallization kinetics [J].
Gradys, Arkadiusz .
POLYMER, 2017, 108 :383-394
[32]   Study of Nonisothermal Crystallization Kinetics of Unstretched and Uniaxially Stretched Electroactive PVDF Composite Films [J].
Mishra, Suvrajyoti ;
Mohanty, Smita ;
Nayak, Sanjay Kumar .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2023, 224 (02)
[33]   Crystallization kinetics of amorphous SiC films: Influence of substrate [J].
Schmidt, H ;
Fotsing, ER ;
Borchardt, G ;
Chassagnon, R ;
Chevalier, S ;
Bruns, M .
APPLIED SURFACE SCIENCE, 2005, 252 (05) :1460-1470
[34]   Characterization tools for polymer thin films [J].
Zeng Xian ;
Yang Zhao-Hui ;
Zhang Xiao-Hua .
ACTA PHYSICA SINICA, 2016, 65 (17)
[35]   Crystallization and morphology of ultrathin films of homopolymers and polymer blends [J].
Prud'homme, Robert E. .
PROGRESS IN POLYMER SCIENCE, 2016, 54-55 :214-231
[36]   Direct Observation of Early-Stage Polymer Crystallization Driven by Surface Wrinkling and Compressive Stress in Thin Films [J].
Zhang, Peng ;
Roth, Stephan V. ;
Mueller-Buschbaum, Peter ;
He, Tian-Bai .
CHINESE JOURNAL OF POLYMER SCIENCE, 2025, 43 (02) :360-367
[37]   Directed Nanoparticle Assembly through Polymer Crystallization [J].
Mei, Shan ;
Staub, Mark ;
Li, Christopher Y. .
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (02) :349-361
[38]   Capillary effects in guided crystallization of organic thin films [J].
Fang, Alta ;
Hailey, Anna K. ;
Grosskopf, Abigail ;
Anthony, John E. ;
Loo, Yueh-Lin ;
Haataja, Mikko .
APL MATERIALS, 2015, 3 (03)
[39]   Study on Lamellar Crystal Orientation and Instable Growth in Polymer Ultrathin Films [J].
Ren, Yijin .
ADVANCED COMPOSITE MATERIALS, PTS 1-3, 2012, 482-484 :1000-1003
[40]   Crystallization and drying in thin sucrose films during panning [J].
Shastry, AV ;
Hartel, RW .
JOURNAL OF FOOD SCIENCE, 1996, 61 (05) :978-981