Polymer Separators for High-Power, High-Efficiency Microbial Fuel Cells

被引:42
作者
Chen, Guang [1 ,2 ]
Wei, Bin [2 ]
Luo, Yong [2 ]
Logan, Bruce E. [2 ]
Hickner, Michael A. [1 ]
机构
[1] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[2] Penn State Univ, Dept Civil & Environm Engn, University Pk, PA 16802 USA
关键词
microbial fuel cell; membrane; poly(vinyl alcohol); Coulombic efficiency; separator; GENERATION; MEMBRANES; CATHODE; PERFORMANCE; CONFIGURATION; ELECTRICITY; CATION; ANODE;
D O I
10.1021/am302301t
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Microbial fuel cells (MFCs) with hydrophilic poly(vinyl alcohol) (PVA) separators showed higher Coulombic efficiencies (94%) and power densities (1220 mW m(-2)) than cells with porous glass fiber separators or reactors without a separator after 32 days of operation. These remarkable increases in both the coublomic efficiency and the power production of the microbial fuel cells were made possible by the separator's unique characteristics of fouling mitigation of the air cathode without a large increase in ionic resistance in the cell. This new type of polymer gel-like separator design will be useful for improving MFC reactor performance by enabling compact cell designs.
引用
收藏
页码:6454 / 6457
页数:4
相关论文
共 28 条
[1]   A New Method for Water Desalination Using Microbial Desalination Cells [J].
Cao, Xiaoxin ;
Huang, Xia ;
Liang, Peng ;
Xiao, Kang ;
Zhou, Yingjun ;
Zhang, Xiaoyuan ;
Logan, Bruce E. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (18) :7148-7152
[2]   Power densities using different cathode catalysts (Pt and CoTMPP) and polymer binders (Nafion and PTFE) in single chamber microbial fuel cells [J].
Cheng, S ;
Liu, H ;
Logan, BE .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (01) :364-369
[3]   Increased power generation in a continuous flow MFC with advective flow through the porous anode and reduced electrode spacing [J].
Cheng, S ;
Liu, H ;
Logan, BE .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (07) :2426-2432
[4]   Increased performance of single-chamber microbial fuel cells using an improved cathode structure [J].
Cheng, S ;
Liu, H ;
Logan, BE .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (03) :489-494
[5]   Enhanced Coulombic efficiency and power density of air-cathode microbial fuel cells with an improved cell configuration [J].
Fan, Yanzhen ;
Hu, Hongqiang ;
Liu, Hong .
JOURNAL OF POWER SOURCES, 2007, 171 (02) :348-354
[6]   Selectivity versus Mobility: Separation of Anode and Cathode in Microbial Bioelectrochemical Systems [J].
Harnisch, Falk ;
Schroeder, Uwe .
CHEMSUSCHEM, 2009, 2 (10) :921-926
[7]   Challenges in microbial fuel cell development and operation [J].
Kim, Byung Hong ;
Chang, In Seop ;
Gadd, Geoffrey M. .
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2007, 76 (03) :485-494
[8]   Power generation using different cation, anion, and ultrafiltration membranes in microbial fuel cells [J].
Kim, Jung Rae ;
Cheng, Shaoan ;
Oh, Sang-Eun ;
Logan, Bruce E. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (03) :1004-1009
[9]   Advances in polymers for anti-biofouling surfaces [J].
Krishnan, Sitaraman ;
Weinman, Craig J. ;
Ober, Christopher K. .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (29) :3405-3413
[10]   Recent advances in the separators for microbial fuel cells [J].
Li, Wen-Wei ;
Sheng, Guo-Ping ;
Liu, Xian-Wei ;
Yu, Han-Qing .
BIORESOURCE TECHNOLOGY, 2011, 102 (01) :244-252