Bis(2,2′-bipyridine-κ2N,N′)chlorocopper(II) 3-carboxybenzenesulfonate trihydrate

被引:7
作者
Cai, L
Xiao, HP
Zhu, LG [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China
[3] Wenzhou Normal Coll, Sch Chem & Mat Sci, Wenzhou 325027, Peoples R China
关键词
D O I
10.1107/S1600536805036044
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [CuCl(C10H8N2)(2)](C7H5O5S) (.) 3H(2)O, the Cu-II ion is coordinated by two 2,2- bipyridine and one chloro ligand in a trigonal-bipyramidal geometry. A hydrogen-bonding network consolidates the crystal structure.
引用
收藏
页码:M2546 / M2547
页数:2
相关论文
共 10 条
[1]   The versatile coordination chemistry of tricyanoethenolate, [(NC)(2)C=C(CN)O](-) [J].
Brandon, EJ ;
Yap, GPA ;
Rheingold, AL ;
Arif, A ;
Miller, JS .
INORGANICA CHIMICA ACTA, 1995, 240 (1-2) :515-518
[2]   The range in static stereochemistry of the cation distortion isomers of the [Cu(chelate)2Cl]+ cation, where chelate = bipy, phen or bipyam.: The low temperature crystal structure (150 K) of [Cu(bipy)2Cl][PF6]•H2O and [Cu(phen)2Cl][BPh4] [J].
Brophy, M ;
Murphy, G ;
O'Sullivan, C ;
Hathaway, B ;
Murphy, B .
POLYHEDRON, 1999, 18 (05) :611-615
[3]  
*BRUK AXS INC, 2002, SADABS VERS 2 03 SAI
[4]   Poly[[aqua(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-4-sulfonatobenzoato-κ2O4:O1] [J].
Fan, SR ;
Xiao, HP ;
Zhang, LP ;
Cai, GQ ;
Zhu, LG .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :M1970-M1972
[5]   Bis(μ-4-sulfobenzoato-κ2O:O′)bis[aqua(2,2′-bi-pyridine-κ2N,N′)copper(II)] [J].
Fan, SR ;
Xiao, HP ;
Zhang, LP ;
Zhu, LG .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M1833-M1835
[7]  
Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020
[8]   Comparative crystallography.: Part 6.: Crystal structures, electronic properties and structural pathways of thirty [Cu(bipy)2X][Y] complexes, where X = Cl-, Br- or I- [J].
O'Sullivan, C ;
Murphy, G ;
Murphy, B ;
Hathaway, B .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11) :1835-1844
[9]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR
[10]   Poly[(1,10-phenanthroline-κ2N,N′)lead(II) μ4-(4-sulfonatobenzoato-κ4O,O′:O",O"′ hydrate] [J].
Zhang, LP ;
Zhu, LG ;
Xiao, HP .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M860-M862