Determination of oxidation states of aluminium, silicon and sulfur

被引：19

作者：

Perino, E ^{[1
]}

Deluigi, MT

Olsina, R

Riveros, JA

机构：

[1] Univ Nacl San Luis, Fac Quim Bioquim & Farm, Area Quim Analit, RA-5700 San Luis, Argentina

[2] Univ Nacl San Luis, Fac Ciencias Fis Matemat & Nat, Dept Fis, Lab Energia Solar, RA-5700 San Luis, Argentina

[3] Univ Nacl Cordoba, Fac Matemat Astron & Fis, RA-5000 Cordoba, Argentina

来源：

X-RAY SPECTROMETRY | 2002年 / 31卷 / 02期

关键词：

D O I：

10.1002/xrs.561

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The lines of the emission spectra originating from vacancies in deep atomic shells change if the elements are in different oxidation states. These changes are shown in this paper, and also the influence that they may have on the calibration of wavelength-dispersive spectrometers and, in consequence, on quantitative analysis by XRF or EPMA. Also, these changes prove to be useful in identifying and, in some cases, quantifying phases in different oxidation states. Copyright (C) 2002 John Wiley Sons, Ltd.

引用

页码：115 / 119

页数：5

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