Sorption enhanced CO2 methanation

被引：146

作者：

Borgschulte, Andreas ^{[1
]}

Gallandat, Noris ^{[1
]}

Probst, Benjamin ^{[1
]}

Suter, Riccardo ^{[1
]}

Callini, Elsa ^{[1
]}

Ferri, Davide ^{[2
]}

Arroyo, Yadira ^{[3
]}

Erni, Rolf ^{[3
]}

Geerlings, Hans ^{[4
]}

Zuettel, Andreas ^{[1
]}

机构：

[1] Lab Hydrogen & Energy, CH-8600 Dubendorf, Switzerland

[2] Lab Solid State Chem & Catalysis, CH-8600 Dubendorf, Switzerland

[3] Empa, Swiss Fed Labs Mat Sci & Technol, Electron Microscopy Ctr, CH-8600 Dubendorf, Switzerland

[4] Delft Univ Technol, NL-2628 BL Delft, Netherlands

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2013年 / 15卷 / 24期

关键词：

CARBON-DIOXIDE; NICKEL; WATER; CATALYSTS; MONOXIDE; HYDROGEN; DESIGN;

D O I：

10.1039/c3cp51408k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The transformation from the fatuous consumption of fossil energy towards a sustainable energy circle is most easily marketable by not changing the underlying energy carrier but generating it from renewable energy. Hydrocarbons can be principally produced from renewable hydrogen and carbon dioxide collected by biomass. However, research is needed to increase the energetic and economic efficiency of the process. We demonstrate the enhancement of CO2 methanation by sorption enhanced catalysis. The preparation and catalytic activity of sorption catalysts based on Ni particles in zeolites is reported. The functioning of the sorption catalysis is discussed together with the determination of the reaction mechanism, providing implications for new ways in catalysis.

引用

页码：9620 / 9625

页数：6

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