An efficient and a novel route for the synthesis of titania via solution combustion of peroxotitanic acid

被引:13
作者
Nagabhushana, Gowdaiahnapalya Puttaiah [1 ]
Ashoka, Siddaramanna [1 ]
Chithaiah, Pallellappa [1 ]
Chandrappa, Gujjarahalli Thimmanna [1 ]
机构
[1] Bangalore Univ, Dept Chem, Bangalore 560001, Karnataka, India
关键词
TiO2; Solution combustion; Semiconductor; Porous materials; NANOCRYSTALLINE TIO2; OXIDES;
D O I
10.1016/j.matlet.2012.09.103
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Despite considerable efforts undertaken in a rapidly developing area of materials research, synthesis of TiO2 nano-powder via green methodologies has a great scientific importance. Here, we present a novel green approach for the synthesis of TiO2 nano-powder by solution combustion process using titanium peroxo complex and tartaric acid (TA) as an intial precursor. The water-soluble peroxo-alpha-hydroxycarboxylato titanium complex, an intermediate precursor mass at external temperature of 500 degrees C, resulted in the oxide of pure anatase phase. This green process involves universal green solvent. hydrogen peroxide and it minimizes the time, energy and cost of the production of TiO2. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:272 / 274
页数:3
相关论文
共 14 条
[1]   Low-temperature chemical synthesis of lead zirconate titanate (PZT) powders free from halides and organics [J].
Camargo, ER ;
Frantti, J ;
Kakihana, M .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (07) :1875-1879
[2]   Effect of preparation conditions on visible photocatalytic activity of titania synthesized by solution combustion method [J].
Cheng Youping ;
Sun Hongqi ;
Jin Wanqin ;
Xu Nanping .
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2007, 15 (02) :178-183
[3]   Synthesis of nanocrystalline TiO2 by tartarate gel method [J].
Dhage, SR ;
Gaikwad, SP ;
Ravi, V .
BULLETIN OF MATERIALS SCIENCE, 2004, 27 (06) :487-489
[4]  
Fujishima A., 1972, Nature, V37, P238
[5]  
Hiromichi I, 2003, J AM CERAM SOC, V86, P1605
[6]   Structure and stability of water soluble (NH4)8[Ti4(C6H4O7)4(O2)4]•8H2O [J].
Kakihana, M ;
Tada, M ;
Shiro, M ;
Petrykin, V ;
Osada, M ;
Nakamura, Y .
INORGANIC CHEMISTRY, 2001, 40 (05) :891-894
[7]   Application of Water-Soluble Titanium Complexes as Precursors for Synthesis of Titanium-Containing Oxides via Aqueous Solution Processes [J].
Kakihana, Masato ;
Kobayashi, Makoto ;
Tomita, Koji ;
Petrykin, Valery .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2010, 83 (11) :1285-1308
[8]   SOL-GEL CHEMISTRY OF TRANSITION-METAL OXIDES [J].
LIVAGE, J ;
HENRY, M ;
SANCHEZ, C .
PROGRESS IN SOLID STATE CHEMISTRY, 1988, 18 (04) :259-341
[9]   Hybrid Sol-Gel Combustion Synthesis of Nanoporous Anatase [J].
Mukherjee, B. ;
Karthik, C. ;
Ravishankar, N. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (42) :18204-18211
[10]   One-pot synthesis of peroxo-titania nanopowder and dual photochemical oxidation in aqueous methanol solution [J].
Shankar, Muthukonda Venkatakrishnan ;
Kako, Tetsuya ;
Wang, Defa ;
Ye, Jinhua .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 331 (01) :132-137