Homoleptic cobalt(II) and cobalt(III) complexes of the sterically demanding bidentate ligand N-ethyl-2-(2′-hydroxy-3′-methylphenyl)benzimidazole

被引：21

作者：

Crane, JD ^{[1
]}

Sinn, E ^{[1
]}

Tann, B ^{[1
]}

机构：

[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, Yorks, England

来源：

POLYHEDRON | 1999年 / 18卷 / 10期

关键词：

cobalt; benzimidazoles; phenolates; bulky ligands; bidentate;

D O I：

10.1016/S0277-5387(99)00028-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homoleptic cobalt(II) and cobalt(III) complexes of the sterically demanding bidentate ligand N-ethyl-2-(2'-hydroxy-3'-methylphenyl)benzimidazole (H-ehmpb) are reported. The bis-ligand cobalt(II) complex Co(ehmpb)(2) has a distorted tetrahedral geometry with Co-N bond lengths of 1.982(3) and 1.976(3) Angstrom, and Co-O bond lengths of 1.915(2) and 1.930(2) Angstrom. The tris-ligand cobalt(III) complex Co(ehmpb), has a distorted mer-octahedral geometry with Co-N bond lengths of 1.879(6), 1.897(6), and 1.895(6) Angstrom, and Co-O bond lengths of 1.923(7), 1.937(7), and 1.937(7) Angstrom. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1527 / 1532

页数：6

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