Sodium hypophosphite decomplexation of acetylenebiscobalthexacarbonyls to cis-olefins

被引：1

作者：

Takai, S ^{[1
]}

Ploypradith, P ^{[1
]}

Hamajima, A ^{[1
]}

Kira, K ^{[1
]}

Isobe, M ^{[1
]}

机构：

[1] Nagoya Univ, Organ Chem Lab, Sch Bioagr Sci, Nagoya, Aichi 4648601, Japan

来源：

SYNLETT | 2002年 / 04期

关键词：

acetylenebiscobalthexacarbonyl; sodium hypophosphite; reductive decomplexation; Nicholas reaction; ciguatoxin;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reductive decomplexation of acetylenebiscobalthexa-carbonyl is best achieved with tri-n-butyltin hydride. Instead of this toxic reagent, sodium hypophosphite monohydrate has proved to be a safe, effective, and economical reagent for such a reductive deconiplexation of biscobalthexacarbonyl acetylenes into the corresponding cis-olefins.

引用

页码：588 / 592

页数：5

共 54 条

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