Sodium hypophosphite decomplexation of acetylenebiscobalthexacarbonyls to cis-olefins

被引：1
作者：
Takai, S [1 ]
Ploypradith, P [1 ]
Hamajima, A [1 ]
Kira, K [1 ]
Isobe, M [1 ]
机构：
[1] Nagoya Univ, Organ Chem Lab, Sch Bioagr Sci, Nagoya, Aichi 4648601, Japan
来源：
SYNLETT | 2002年 / 04期
关键词：
acetylenebiscobalthexacarbonyl; sodium hypophosphite; reductive decomplexation; Nicholas reaction; ciguatoxin;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reductive decomplexation of acetylenebiscobalthexa-carbonyl is best achieved with tri-n-butyltin hydride. Instead of this toxic reagent, sodium hypophosphite monohydrate has proved to be a safe, effective, and economical reagent for such a reductive deconiplexation of biscobalthexacarbonyl acetylenes into the corresponding cis-olefins.
引用
收藏
页码：588 / 592
页数：5
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