Efficient Light Harvesters Based on the 10-(1,3-Dithiol-2-ylidene)anthracene Core

被引：16

作者：

Bouit, Pierre-Antoine ^{[1
]}

Infantes, Lourdes ^{[2
]}

Calbo, Joaquin ^{[3
]}

Viruela, Rafael ^{[3
]}

Orti, Enrique ^{[3
]}

Luis Delgado, Juan ^{[1
]}

Martin, Nazario ^{[1
,4
]}

机构：

[1] IMDEA Nanociencia, Madrid 28049, Spain

[2] CSIC, Inst Quim Fis Rocasolano, E-28006 Madrid, Spain

[3] Univ Valencia, Inst Ciencia Mol, Paterna 46980, Spain

[4] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 16期

关键词：

ELECTRON-TRANSFER; DYE;

D O I：

10.1021/ol401841u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three new push-pull chromophores based on the 10-(1,3-dithiol-2-ylidene)anthracene core were synthesized and fully characterized. The new chromophores display broad absorption spectra, nearly covering the whole visible region, with high extinction coefficients. Electrochemistry and theoretical calculations allowed the understanding of these singular electronic properties. The molecular structures were unambiguously confirmed by X-ray diffraction.

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收藏

页码：4166 / 4169

页数：4

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