Inverse phase transfer catalysis.: III.: Optimization of the epoxidation reaction of α,β-unsaturated ketones by hydrogen peroxide.

被引：33

作者：

Boyer, B

Hambardzoumian, A

Roque, JP

机构：

[1] Univ Montpellier 2, Chim Organ Phys Lab, F-34095 Montpellier 5, France

[2] Yerevan State Univ, Dept Phys Chem, Yerevan 375049, Armenia

来源：

TETRAHEDRON | 1999年 / 55卷 / 19期

关键词：

epoxidation; hydrogen peroxide; surfactant; phase-transfer catalysis;

D O I：

10.1016/S0040-4020(99)00270-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The epoxidation of chalcone using hydrogen peroxide in the presence of a base in a two-phase medium system following the so-called Inverse Phase Transfer Catalysis (IPTC) process was investigated. Careful examination of various parameters including surfactant concentration, pH, H2O2 decomposition side-reactions and epoxide ring-opening, allowed us to determine optimal experimental conditions (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：6147 / 6152

页数：6

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