Self-Assembly and Visible-Light Photocatalytic Properties of W/Nb Mixed-Addendum Polyoxometalate and Transition-Metal Cations

被引：23

作者：

Huang, Peng ^{[1
]}

Qin, Chao ^{[1
]}

Wang, Xin-Long ^{[1
]}

Sun, Chun-Yi ^{[1
]}

Jiao, Yan-Qing ^{[1
]}

Xing, Yan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Funct Mat Chem,Natl & Local United Engn Lab, Key Lab Polyoxometalate Sci,Minist Educ, Changchun 130024, Jilin, Peoples R China

来源：

CHEMPLUSCHEM | 2013年 / 78卷 / 08期

关键词：

niobium; photocatalysis; polyoxometalates; synthetic methods; tungsten; COPPER-ORGANIC CATIONS; HYDROGEN EVOLUTION; SOLID-SOLUTION; WATER; CATALYST; OXIDATION; CHEMISTRY; CLUSTERS; H-2; DECOMPOSITION;

D O I：

10.1002/cplu.201300175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Making light work: Three novel W/Nb mixed-addendum polyoxometalates, which all contain the {SiNb3W9O40} cluster, have been synthesized by conventional aqueous methods. Visible-light photocatalytic H2 evolution activity (see figure) was observed for two of the compounds, with H2PtCl6 as a cocatalyst and triethylamine as a sacrificial electron donor. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：775 / 779

页数：5