Adsorption capacity of kelp- like electrospun nanofibers immobilized with bayberry tannin for uranium( VI) extraction from seawater

被引:44
作者
Meng, Jie [1 ,2 ]
Lin, Xiaoyan [1 ,2 ]
Li, Haonan [1 ]
Zhang, Yida [1 ]
Zhou, Jian [2 ]
Chen, Yan [1 ,2 ]
Shang, Ran [3 ]
Luo, Xuegang [2 ]
机构
[1] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, Mianyang 621010, Sichuan, Peoples R China
[2] Minist Educ, Engn Res Ctr Biomass Mat, Mianyang 621010, Sichuan, Peoples R China
[3] State Key Lab NBC Protect Civilian, Beijing 102205, Peoples R China
关键词
ONE-POT SYNTHESIS; EFFICIENT REMOVAL; AQUEOUS-SOLUTION; HYDROTHERMAL CARBON; WASTE-WATER; RECOVERY; CHITOSAN; IONS; ADSORBENT; SORPTION;
D O I
10.1039/c8ra09297d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The extraction of uranium(vi) from seawater is of paramount interest to meet the rapid expansion of global energy needs. A novel gelatin/PVA composite nanofiber band loaded with bayberry tannin (GPNB-BT) was used to extract uranium(vi) from simulated seawater in this study. It was fabricated by electrostatic spinning and crosslinking, and characterized by SEM, EDX, FTIR, and XPS. Batch experiments were carried out to investigate the adsorption of uranium(vi) onto GPNB-BT. Simultaneously, the regeneration-reuse process of the GPNB-BT was determined and illustrated here. The GPNB-BT exhibited excellent adsorption and regeneration performance, and a maximum adsorption capacity of 254.8 mg g(-1) toward uranium(vi) was obtained at 298.15 K, pH = 5.5. Further, the regeneration rate for uranium did not decrease significantly after five cycles. Moreover, even at an extremely low initial concentration of 3 g L-1 in the simulated seawater for 24 h, GPNB-BT showed an ultrahigh adsorption rate of more than 90% and adsorption capacity of 7.2 g g(-1) for uranium. The high density of adjacent phenolic hydroxyl groups and the specific surface area of GPNB-BT improved the adsorption ability of GPNB-BT for uranium. Therefore, the GPNB-BT was shown to have an application prospect for the effective extraction of uranium(vi) from seawater.
引用
收藏
页码:8091 / 8103
页数:13
相关论文
共 53 条
[1]   The effectiveness of ion exchange resins in separating uranium and thorium from rare earth elements in acidic aqueous sulfate media. Part 2. Chelating resins [J].
Ang, Kwang Loon ;
Li, Dan ;
Nikoloski, Aleksandar N. .
MINERALS ENGINEERING, 2018, 123 :8-15
[2]   Synthesis and characterization of tannin-immobilized hydrotalcite as a potential adsorbent of heavy metal ions in effluent treatments [J].
Anirudhan, Thayyath S. ;
Suchithra, Padmajan S. .
APPLIED CLAY SCIENCE, 2008, 42 (1-2) :214-223
[3]   Three novel triazine-based materials with different O/S/N set of donor atoms: One-step preparation and comparison of their capability in selective separation of uranium [J].
Bai, Chiyao ;
Zhang, Meicheng ;
Li, Bo ;
Tian, Yin ;
Zhang, Shuang ;
Zhao, Xiaosheng ;
Li, Yang ;
Wang, Lei ;
Ma, Lijian ;
Li, Shoujian .
JOURNAL OF HAZARDOUS MATERIALS, 2015, 300 :368-377
[4]   A review of potentially low-cost sorbents for heavy metals [J].
Bailey, SE ;
Olin, TJ ;
Bricka, RM ;
Adrian, DD .
WATER RESEARCH, 1999, 33 (11) :2469-2479
[5]  
Cheng YM, 2011, CHINESE J CHEM ENG, V19, P592
[6]   IMMOBILIZED TANNIN - A NOVEL ADSORBENT FOR PROTEIN AND METAL-ION [J].
CHIBATA, I ;
TOSA, T ;
MORI, T ;
WATANABE, T ;
SAKATA, N .
ENZYME AND MICROBIAL TECHNOLOGY, 1986, 8 (03) :130-136
[7]   Competitive adsorption of heavy metals and uranium on soil constituents and microorganism [J].
Choi, J ;
Park, JW .
GEOSCIENCES JOURNAL, 2005, 9 (01) :53-61
[8]   Novel poly(imide dioxime) sorbents: Development and testing for enhanced extraction of uranium from natural seawater [J].
Das, S. ;
Brown, S. ;
Mayes, R. T. ;
Janke, C. J. ;
Tsouris, C. ;
Kuo, L. -J. ;
Gill, G. ;
Dai, S. .
CHEMICAL ENGINEERING JOURNAL, 2016, 298 :125-135
[9]   Tannins characterization in historic leathers by complementary analytical techniques ATR-FTIR, UV-Vis and chemical tests [J].
Falcao, Lina ;
Araujo, Maria Eduarda M. .
JOURNAL OF CULTURAL HERITAGE, 2013, 14 (06) :499-508
[10]  
Gajowiak A, 2009, PRZEM CHEM, V88, P190