Optical properties of cerium doped oxyfluoroborate glass

被引:34
作者
Bahadur, A. [1 ]
Dwivedi, Y. [1 ]
Rai, S. B. [1 ]
机构
[1] Banaras Hindu Univ, Dept Phys, Laser & Spect Lab, Varanasi 221005, Uttar Pradesh, India
关键词
Oxyfluoroborate glass; Absorption; Optical band gap; Ce(3+)ion;
D O I
10.1016/j.saa.2013.03.066
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Cerium doped oxyfluoroborate glasses have been prepared and its spectroscopic properties have been discussed. It is found that the absorption edge shifts towards the lower energy side for the higher concentration of cerium dopant. Optical band gap for these glasses have been calculated and it is found that the number of non-bridging oxygen increases with cerium content. The emission spectra of these glasses have been recorded using UV laser radiations (266 and 355 nm) and it is observed that these glasses show bright blue emission. On the basis of excitation and emission spectra we have reported the existence of at least two different emission centers of Ce(3+)ions. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:400 / 403
页数:4
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