Synthesis, Structures, and Properties of Two Novel Coordination Polymers with a V-shaped Diphosphonate Ligand

被引：5
作者：
Lv, Xiaoxia [1 ,2 ]
Tang, Sifu [1 ]
Li, Liangjun [1 ,2 ]
Xu, Xianrui [1 ,2 ]
Zhao, Xuebo [1 ]
机构：
[1] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Diphosphonate ligand; V-shape; Crystal structure; X-ray diffraction; Infrared spectroscopy; METAL-ORGANIC FRAMEWORKS; TRINUCLEAR (NICUNIII)-CU-II-NI-II COMPLEXES; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; CHAIN; CO2; SEPARATION; NI;
D O I：
10.1002/zaac.201300185
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel coordination polymers, [Cu(H2L)(bipy)(H2O)(2)]center dot H2O (1) and [Ni-2(H2L)(bipy)(2.5)(H2O)(6)]center dot(H2L)center dot 7H(2)O (2) with the V-shaped diphosphonate ligand (2,4,6-trimethyl-1,3-phenylene) bis(methylene) diphosphonic acid (H4L) were synthesized via hydrothermal reactions in the presence of auxiliary ligand 4,4'-bipyridine. Their structures were determined by single-crystal X-ray diffraction and further characterized by elemental analysis, infrared spectroscopy (IR), and thermogravimetric analysis (TGA). Compound 1 crystallizes in the Pnma space group and compound 2 crystallizes in the P2(1)2(1)2 space group. They display square-grid layer and bilayer two-dimensional network, respectively.
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收藏
页码：1845 / 1849
页数：5
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