Synthesis and characterization of polymeric [CdBr2(H(2)biim)](n)

被引：27

作者：

Hester, CA

Collier, HL

Baughman, RG

机构：

[1] UNIV MISSOURI,DEPT CHEM,ROLLA,MO 65401

[2] NE MISSOURI STATE UNIV,DIV SCI,KIRKSVILLE,MO 63501

来源：

POLYHEDRON | 1996年 / 15卷 / 23期

关键词：

2,2'-biimidazole; cadmium bromide; crystal structure; coordination polymer; self-assembly;

D O I：

10.1016/0277-5387(96)00170-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CdBr2 with H(2)biim (H(2)biim = 2,2'-biimidazole) in an aqueous solution affords the linear coordination polymer [CdBr2(H(2)biim)](n). An X-ray crystallographic study of this complex reveals a 1-dimensional chain in which adjacent pseudo-octahedrally coordinated Cd atoms are bridged in a bis(mu-bromo) fashion. Published by Elsevier Science Ltd

引用

页码：4255 / 4258

页数：4

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