Thermal analyses and spectral characterization of some synthesized metal(II) Schiff base complexes

被引：13

作者：

Jain, Rajendra K. ^{[1
]}

Mishra, A. P. ^{[1
]}

Gupta, Priya ^{[1
]}

机构：

[1] Dr HS Gour Cent Univ, Dept Chem, Synthet Inorgan & Coordinat Chem Labs, Sagar 470003, Madhya Pradesh, India

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2012年 / 110卷 / 02期

关键词：

Schiff base complexes; Spectral analyses; Thermal analyses; COPPER(II) COMPLEXES; NICKEL(II); DECOMPOSITION; COBALT(II); BEHAVIOR; CU(II); CO(II); NI(II);

D O I：

10.1007/s10973-012-2401-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Schiff base metal complexes derived from 2-thiophenecarboxylidine-4-anisidine, 3,4-dihydroxy-5-nitrobenzylidine-2-amino-5-methylthiazole and 3,4-dihydroxy-5-nitrobenzylidine-4-chloroaniline have been synthesized and characterized by elemental analysis, IR, UV-Vis, molar conductance and thermal analyses. The complexes are coloured and stable in air at room temperature. The complexes exhibit coordination number to be 4 and 6. The thermal behaviour of metal complexes shows that the hydrated complexes lose water molecules of hydration in the first and then is immediately followed by decomposition of ligand molecules in the subsequent steps.

引用

页码：529 / 534

页数：6

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