A bifunctional metal-organic framework featuring the combination of open metal sites and Lewis basic sites for selective gas adsorption and heterogeneous cascade catalysis

被引：137
作者：
He, Hongming [1 ,2 ]
Sun, Fuxing [1 ]
Aguila, Briana [2 ]
Perman, Jason A. [2 ]
Ma, Shengqian [2 ]
Zhu, Guangshan [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[2] Univ S Florida, Dept Chem, 4202 East Fowler Ave, Tampa, FL 33620 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 39期
关键词：
WHITE-LIGHT EMISSION; CARBON-DIOXIDE CAPTURE; IMIDAZOLATE FRAMEWORKS; SORPTION PROPERTIES; AMBIENT CONDITIONS; SINGLE-CRYSTAL; CO2; UPTAKE; MOF; HYDROCARBONS; SEPARATION;
D O I：
10.1039/c6ta05098k
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A bifunctional MOF ( JUC-199) featuring dual functionality, open metal sites ( Zn2+) and Lewis basic sites (-NH2), has been successfully synthesized using a custom-designed ligand. JUC-199 demonstrated good selective gas sorption behaviours with IAST selectivity values of 9, 30, 37 and 64 at 298 K and 101 kPa for CO2/CH4, CO2/N-2, C2H6/CH4 and C2H4/CH4 respectively; surpassing those of most MOFs reported thus far. Moreover, JUC-199 can serve as a heterogeneous cascade catalyst to efficiently catalyse the tandem one-pot deacatalization-Knoevenagel condensation reaction.
引用
收藏
页码：15240 / 15246
页数：7
相关论文
共 73 条
[31]   Cooperative multi-catalyst systems for one-pot organic transformations [J].
Lee, JM ;
Na, Y ;
Han, H ;
Chang, S .
CHEMICAL SOCIETY REVIEWS, 2004, 33 (05) :302-312
[32]   A new site-isolated acid-base bifunctional metal-organic framework for one-pot tandem reaction [J].
Lee, Yu-Ri ;
Chung, Young-Min ;
Ann, Wha-Seung .
RSC ADVANCES, 2014, 4 (44) :23064-23067
[33]   Applications of metal-organic frameworks featuring multi-functional sites [J].
Li, Baiyan ;
Chrzanowski, Matthew ;
Zhang, Yiming ;
Ma, Shengqian .
COORDINATION CHEMISTRY REVIEWS, 2016, 307 :106-129
[34]   Metal-Organic Framework Based upon the Synergy of a Bronsted Acid Framework and Lewis Acid Centers as a Highly Efficient. Heterogeneous Catalyst for Fixed-Bed Reactions [J].
Li, Baiyan ;
Leng, Kunyue ;
Zhang, Yiming ;
Dynes, James J. ;
Wang, Jian ;
Hu, Yongfeng ;
Ma, Dingxuan ;
Shi, Zhan ;
Zhu, Liangkui ;
Zhang, Daliang ;
Sun, Yinyong ;
Chrzanowski, Matthew ;
Ma, Shengqian .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (12) :4243-4248
[35]   A strategy toward constructing a bifunctionalized MOF catalyst: post-synthetic modification of MOFs on organic ligands and coordinatively unsaturated metal sites [J].
Li, Baiyan ;
Zhang, Yiming ;
Ma, Dingxuan ;
Li, Lu ;
Li, Guanghua ;
Li, Guodong ;
Shi, Zhan ;
Feng, Shouhua .
CHEMICAL COMMUNICATIONS, 2012, 48 (49) :6151-6153
[36]   Comparison of Cu-BTC and zeolite 13X for adsorbent based CO2 separation [J].
Liang, Zhijian ;
Marshall, Marc ;
Chaffee, Alan L. .
GREENHOUSE GAS CONTROL TECHNOLOGIES 9, 2009, 1 (01) :1265-1271
[37]   Amine-functionalized metal-organic frameworks: structure, synthesis and applications [J].
Lin, Yichao ;
Kong, Chunlong ;
Chen, Liang .
RSC ADVANCES, 2016, 6 (39) :32598-32614
[38]   Direct synthesis of amine-functionalized MIL-101(Cr) nanoparticles and application for CO2 capture [J].
Lin, Yichao ;
Kong, Chunlong ;
Chen, Liang .
RSC ADVANCES, 2012, 2 (16) :6417-6419
[39]   An N-rich metal-organic framework with an rht topology: high CO2 and C2 hydrocarbons uptake and selective capture from CH4 [J].
Liu, Kang ;
Li, Baiyan ;
Li, Yi ;
Li, Xu ;
Yang, Fen ;
Zeng, Guang ;
Peng, Yu ;
Zhang, Zhijuan ;
Li, Guanghua ;
Shi, Zhan ;
Feng, Shouhua ;
Song, Datong .
CHEMICAL COMMUNICATIONS, 2014, 50 (39) :5031-5033
[40]   Multifunctional lanthanide-organic frameworks for fluorescent sensing, gas separation and catalysis [J].
Liu, Xiaobin ;
Lin, Huan ;
Xiao, Zhenyu ;
Fan, Weidong ;
Huang, Ao ;
Wang, Rongming ;
Zhang, Liangliang ;
Sun, Daofeng .
DALTON TRANSACTIONS, 2016, 45 (09) :3743-3749
12345678