Synthesis and structural characterization of three dinuclear Copper(II) complexes incorporating pyrazolyl-derived ligands

被引：8

作者：

Soltani, Behzad ^{[2
]}

Sadr, Moayad Hossaini ^{[2
]}

Engle, James T. ^{[3
]}

Ziegler, Christopher J. ^{[3
]}

Joo, Sang Woo ^{[1
]}

Hanifehpour, Younes ^{[1
]}

机构：

[1] Yeungnam Univ, WCU Nano Res Ctr, Sch Mech Engn, Kyongsan 712749, South Korea

[2] Azarbaijan Univ Shahid Madani, Dept Chem, Tabriz, Iran

[3] Univ Akron, Dept Chem, Akron, OH 44325 USA

来源：

TRANSITION METAL CHEMISTRY | 2012年 / 37卷 / 08期

基金：

新加坡国家研究基金会;

关键词：

TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; BINUCLEAR; SILVER(I); CHEMISTRY; CU(I);

D O I：

10.1007/s11243-012-9639-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new binuclear copper complexes of formulae (1), (2) and (3) (Pz(Me3) = 3,4,5-trimethylpyrazole, Pz(Ph2Me) = 4-methyl-3,5-diphenylpyrazole and Pz(PhMe) = 3-methyl-5-phenylpyrazole) have been synthesized and characterized by chemical analysis, FTIR and P-31 NMR spectroscopy and single-crystal X-ray diffraction. Complex 1 is a doubly bromo-bridged dimer, while complexes 2 and 3 are chloro-bridged dimers. The Cu(II) centers are in a distorted tetrahedral geometry for 1 and 2 and a distorted square pyramidal N2Cl3 environment for 3.

引用

页码：687 / 694

页数：8

共 50 条

[21] Synthesis, structural characterization, and magnetic properties of dinuclear, tetranuclear, and heptanuclear copper(II), cobalt(II/III), and nickel(II) complexes of Schiff-base ligands
Tandon, Santokh S.
Bunge, Scott D.
Thompson, Laurence K.
Patel, Neil
Motry, Douglas
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[22] Synthesis and structural characterization of copper(II) bishexafluoroacetylacetonate complexes with N-donor ligands
Delgado, S
Muñoz, A
Medina, ME
Pastor, CJ
INORGANICA CHIMICA ACTA, 2006, 359 (01) : 109 - 117
[23] New Energetic Copper(II) Complexes With Pyrazolyl Type Ligands
Oz, Sevi
Svoboda, Ingrid
Kurtaran, Raif
Aksu, Mecit
Sari, Musa
Kunduraci, Melike
Atakol, Orhan
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (02): : 257 - 262
[24] Three Copper(II) Complexes of a "Tritopic" Hydrazone Ligand: Synthesis and Structural Characterization
Qin, Suni
Nie, Chuanli
Weng, Zhehui
Chen, Zilu
Liang, Fupei
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (14-15): : 2294 - 2299
[25] Dinuclear copper(II) complexes with valsartan. Synthesis, characterization and cytotoxicity
Etcheverry, Susana B.
Di Virgilio, Ana L.
Nascimento, Otaciro R.
Williams, Patricia A. M.
JOURNAL OF INORGANIC BIOCHEMISTRY, 2012, 107 (01) : 25 - 33
[26] Synthesis and Characterization of Some Dinuclear Tetraaza Macrocyclic Complexes of Copper(II)
Synth React Inorg Metal Org Chem, 1 (87):
[27] Synthesis and characterization of some dinuclear tetraaza macrocyclic complexes of copper(II)
Singh, M
Nayan, R
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1998, 28 (01): : 87 - 104
[28] SYNTHESIS AND CHARACTERIZATION OF OSMIUM(II) COMPLEXES INCORPORATING POLYPYRIDYL BRIDGING LIGANDS
RICHTER, MM
BREWER, KJ
INORGANICA CHIMICA ACTA, 1991, 180 (01) : 125 - 131
[29] Three new dinuclear silver(I) complexes derived from pyrazolyl type ligands -: Crystal structure and thermal decomposition
Atakol, O.
Fuess, H.
Kurtaran, R.
Akay, A.
Arici, C.
Ergun, Ue.
Emreguel, K. C.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 90 (02) : 517 - 523
[30] Synthesis, characterization and biological activity of copper(II) complexes with ligands derived from β-amino acids
Andriana M. Bukonjić
Dušan Lj. Tomović
Ana S. Stanković
Verica V. Jevtić
Zoran R. Ratković
Jovana V. Bogojeski
Jelena Z. Milovanović
Dragana B. Đorđević
Aleksandar N. Arsenijević
Marija Z. Milovanović
Ivan Potočňák
Srećko R. Trifunović
Gordana P. Radić
Transition Metal Chemistry, 2019, 44 : 65 - 76

← 1 2 3 4 5 →