Synthesis and structural characterization of three dinuclear Copper(II) complexes incorporating pyrazolyl-derived ligands

被引：8

作者：

Soltani, Behzad ^{[2
]}

Sadr, Moayad Hossaini ^{[2
]}

Engle, James T. ^{[3
]}

Ziegler, Christopher J. ^{[3
]}

Joo, Sang Woo ^{[1
]}

Hanifehpour, Younes ^{[1
]}

机构：

[1] Yeungnam Univ, WCU Nano Res Ctr, Sch Mech Engn, Kyongsan 712749, South Korea

[2] Azarbaijan Univ Shahid Madani, Dept Chem, Tabriz, Iran

[3] Univ Akron, Dept Chem, Akron, OH 44325 USA

来源：

TRANSITION METAL CHEMISTRY | 2012年 / 37卷 / 08期

基金：

新加坡国家研究基金会;

关键词：

TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; BINUCLEAR; SILVER(I); CHEMISTRY; CU(I);

D O I：

10.1007/s11243-012-9639-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new binuclear copper complexes of formulae (1), (2) and (3) (Pz(Me3) = 3,4,5-trimethylpyrazole, Pz(Ph2Me) = 4-methyl-3,5-diphenylpyrazole and Pz(PhMe) = 3-methyl-5-phenylpyrazole) have been synthesized and characterized by chemical analysis, FTIR and P-31 NMR spectroscopy and single-crystal X-ray diffraction. Complex 1 is a doubly bromo-bridged dimer, while complexes 2 and 3 are chloro-bridged dimers. The Cu(II) centers are in a distorted tetrahedral geometry for 1 and 2 and a distorted square pyramidal N2Cl3 environment for 3.

引用

页码：687 / 694

页数：8

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