Fluorinated graphene based electrodes for high performance primary lithium batteries

被引：74

作者：

Damien, D. ^{[1
]}

Sudeep, P. M. ^{[1
,2
]}

Narayanan, T. N. ^{[3
]}

Anantharaman, M. R. ^{[2
]}

Ajayan, P. M. ^{[4
]}

Shaijumon, M. M. ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Thiruvananthapuram, Thiruvananthapuram 695016, Kerala, India

[2] Cochin Univ Sci & Technol, Dept Phys, Cochin 682022, Kerala, India

[3] CSIR, Cent Electro Chem Res Inst, Karaikkudi 630006, Tamil Nadu, India

[4] Rice Univ, Dept Mech Engn & Mat Sci, Houston, TX 77005 USA

来源：

RSC ADVANCES | 2013年 / 3卷 / 48期

关键词：

GRAPHITE FLUORIDES; ELECTROCHEMICAL PROPERTIES; DISCHARGE MECHANISM; CARBON NANOFIBRES; CATHODE; TEMPERATURE;

D O I：

10.1039/c3ra45377d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A single step strategy capable of improving specific capacity, power capability and faradic yield of a Li/CFx battery system is developed. The excellent electrochemical performance achieved here using fluorinated graphene with a very low fluorine content (x = 0.22) could lead to the development of highly efficient primary battery systems with low cost and minimum environmental impact.

引用

页码：25702 / 25706

页数：5

共 22 条

[11] Physical characteristics and rate performance of (CFx)n (0.33 < x < 0.66) in lithium batteries [J].

Lam, P ;

Yazami, R .

JOURNAL OF POWER SOURCES, 2006, 153 (02) :354-359

[12] Synthesis of Fluorinated Graphene Oxide and its Amphiphobic Properties [J].

Mathkar, Akshay ;

Narayanan, T. N. ;

Alemany, Lawrence B. ;

Cox, Paris ;

Patrick Nguyen ;

Gao, Guanhui ;

Chang, Patricia ;

Romero-Aburto, Rebeca ;

Mani, Sendurai A. ;

Ajayan, P. M. .

PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, 2013, 30 (03) :266-272

[13] Tunable electrochemical properties of fluorinated graphene [J].

Meduri, Praveen ;

Chen, Honghao ;

Xiao, Jie ;

Martinez, Jayson J. ;

Carlson, Thomas ;

Zhang, Ji-Guang ;

Deng, Z. Daniel .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (27) :7866-7869

[14] Hybrid CFx-Ag2V4O11 as a high-energy, power density cathode for application in an underwater acoustic microtransmitter [J].

Meduri, Praveen ;

Chen, Honghao ;

Chen, Xilin ;

Xiao, Jie ;

Gross, Mark E. ;

Carlson, Thomas J. ;

Zhang, Ji-Guang ;

Deng, Z. Daniel .

ELECTROCHEMISTRY COMMUNICATIONS, 2011, 13 (12) :1344-1348

[15] ON THE STRUCTURE OF GRAPHITE FLUORIDE [J].

TOUHARA, H ;

KADONO, K ;

FUJII, Y ;

WATANABE, N .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1987, 544 (01) :7-20

[16] MECHANISM OF REDUCTION OF FLUOROGRAPHITE CATHODE [J].

WHITTINGHAM, MS .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (04) :526-527

[17] Fluorinated carbon nanofibres for high energy and high power densities primary lithium batteries [J].

Yazami, R. ;

Hamwi, A. ;

Guerin, K. ;

Ozawa, Y. ;

Dubois, M. ;

Giraudet, J. ;

Masin, F. .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (07) :1850-1855

[18] Carbon-coated fluorinated graphite for high energy and high power densities primary lithium batteries [J].

Zhang, Q. ;

D'Astorg, S. ;

Xiao, P. ;

Zhang, X. ;

Lu, L. .

JOURNAL OF POWER SOURCES, 2010, 195 (09) :2914-2917

[19] Enhancement of discharge performance of Li/CFx cell by thermal treatment of CFx cathode material [J].

Zhang, Sheng S. ;

Foster, Donald ;

Read, Jeffrey .

JOURNAL OF POWER SOURCES, 2009, 188 (02) :601-605

[20] Electrochemical characteristic and discharge mechanism of a primary Li/CFx cell [J].

Zhang, Sheng S. ;

Foster, Donald ;

Wolfenstine, Jeff ;

Read, Jeffrey .

JOURNAL OF POWER SOURCES, 2009, 187 (01) :233-237

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