Fluorinated graphene based electrodes for high performance primary lithium batteries

被引:74
作者
Damien, D. [1 ]
Sudeep, P. M. [1 ,2 ]
Narayanan, T. N. [3 ]
Anantharaman, M. R. [2 ]
Ajayan, P. M. [4 ]
Shaijumon, M. M. [1 ]
机构
[1] Indian Inst Sci Educ & Res Thiruvananthapuram, Thiruvananthapuram 695016, Kerala, India
[2] Cochin Univ Sci & Technol, Dept Phys, Cochin 682022, Kerala, India
[3] CSIR, Cent Electro Chem Res Inst, Karaikkudi 630006, Tamil Nadu, India
[4] Rice Univ, Dept Mech Engn & Mat Sci, Houston, TX 77005 USA
关键词
GRAPHITE FLUORIDES; ELECTROCHEMICAL PROPERTIES; DISCHARGE MECHANISM; CARBON NANOFIBRES; CATHODE; TEMPERATURE;
D O I
10.1039/c3ra45377d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A single step strategy capable of improving specific capacity, power capability and faradic yield of a Li/CFx battery system is developed. The excellent electrochemical performance achieved here using fluorinated graphene with a very low fluorine content (x = 0.22) could lead to the development of highly efficient primary battery systems with low cost and minimum environmental impact.
引用
收藏
页码:25702 / 25706
页数:5
相关论文
共 22 条
[1]   Electrochemical performance of low temperature fluorinated graphites used as cathode in primary lithium batteries [J].
Delabarre, C. ;
Dubois, M. ;
Giraudet, J. ;
Guerin, K. ;
Hamwi, A. .
CARBON, 2006, 44 (12) :2543-2548
[2]   Characterizing Graphene, Graphite, and Carbon Nanotubes by Raman Spectroscopy [J].
Dresselhaus, M. S. ;
Jorio, A. ;
Saito, R. .
ANNUAL REVIEW OF CONDENSED MATTER PHYSICS, VOL 1, 2010, 1 :89-108
[3]   Tuning the discharge potential of fluorinated carbon used as electrode in primary lithium battery [J].
Dubois, M. ;
Guerin, K. ;
Zhang, W. ;
Ahmad, Y. ;
Hamwi, A. ;
Fawal, Z. ;
Kharbache, H. ;
Masin, F. .
ELECTROCHIMICA ACTA, 2012, 59 :485-491
[4]   Comparative performances for primary lithium batteries of some covalent and semi-covalent graphite fluorides [J].
Giraudet, Jerome ;
Delabarre, Celine ;
Guerin, Katia ;
Dubois, Marc ;
Masin, Francis ;
Hamwi, Andre .
JOURNAL OF POWER SOURCES, 2006, 158 (02) :1365-1372
[5]   Improvements of the electrochemical features of graphite fluorides in primary lithium battery by electrodeposition of polypyrrole [J].
Groult, H. ;
Julien, C. M. ;
Bahloul, A. ;
Leclerc, S. ;
Briot, E. ;
Mauger, A. .
ELECTROCHEMISTRY COMMUNICATIONS, 2011, 13 (10) :1074-1076
[6]   Hybrid-type graphite fluoride as cathode material in primary lithium batteries [J].
Guérin, K ;
Yazami, R ;
Hamwi, A .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (06) :A159-A162
[7]   Electrochemical discharge mechanism of fluorinated graphite used as electrode in primary lithium batteries [J].
Guerin, Katia ;
Dubois, Marc ;
Hamwi, Andre .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2006, 67 (5-6) :1173-1177
[8]   Applicative performances of fluorinated carbons through fluorination routes: A review [J].
Guerin, Katia ;
Dubois, Marc ;
Houdayer, Axel ;
Hamwi, Andre .
JOURNAL OF FLUORINE CHEMISTRY, 2012, 134 :11-17
[9]   GRAPHITE FLUORIDES PREPARED AT ROOM-TEMPERATURE .1. SYNTHESIS AND CHARACTERIZATION [J].
HAMWI, A ;
DAOUD, M ;
COUSSEINS, JC .
SYNTHETIC METALS, 1988, 26 (01) :89-98
[10]   Unraveling Structural Models of Graphite Fluorides by Density Functional Theory Calculations [J].
Han, Sang Soo ;
Yu, Ted H. ;
Merinov, Boris V. ;
van Duin, Adri C. T. ;
Yazami, Rachid ;
Goddard, William A., III .
CHEMISTRY OF MATERIALS, 2010, 22 (06) :2142-2154