The effects of UV irradiation in azo-derivatives

被引:5
作者
Ionita, Ionica [1 ,2 ,3 ]
Albu, Ana-Maria
Radulescu, Cristiana [1 ]
Dulama, Ioana Daniela [4 ]
Gavrila, Ionela [2 ]
机构
[1] Valahia Univ Targoviste, Fac Sci & Arts, Dept Sci, 18-24 Unirii Bdvl, Targoviste 130082, Romania
[2] Univ Bucharest, Dept Polymer Sci, Bucharest R-010072, Romania
[3] Romanian Acad, Ctr Organ Chem, Bucharest R-060023, Romania
[4] Valahia Univ Targoviste, ICSTM, Targoviste R-130082, Romania
来源
ADVANCED TOPICS IN OPTOELECTRONICS, MICROELECTRONICS, AND NANOTECHNOLOGIES VI | 2012年 / 8411卷
关键词
photochromic; photoisomerization; irradiation; azo dye; CONTAINING POLYMERS;
D O I
10.1117/12.964412
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
From all type of external stimuli the light rays are most commonly used because it involves only photochemical processes easily to control. One of the most studied of photochemical processes is photoisomerization groups, in particular the azobenzene groups. The azobenzene and his derivatives, known for Z(sin)-E(anti) reversible photoisomerization properties, have been extensively used as functional groups to synthesize various photosensitive compounds. The UV irradiation at different time of modified maleic anhydride - styrene copolymers with azo dye solutions were with UV light to increase the rate of Z(sin)-E(anti) isomerisation. The changes in the spectral absorption domain for azo compounds, a decrease in optic absorbance after irradiation, with a predisposition to come back at primary value was made with SECOMAMS750 UV-Vis spectrophotometer.
引用
收藏
页数:6
相关论文
共 11 条
[1]   THE COPOLYMERIZATION OF STYRENE AND MALEIC ANHYDRIDE [J].
ALFREY, T ;
LAVIN, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1945, 67 (11) :2044-2045
[2]   THERMAL CIS-TRANS ISOMERIZATION RATES OF AZOBENZENES BOUND IN THE SIDE-CHAIN OF SOME COPOLYMERS AND BLENDS [J].
BARRETT, C ;
NATANSOHN, A ;
ROCHON, P .
MACROMOLECULES, 1994, 27 (17) :4781-4786
[3]   SELECTED ASPECTS OF PHOTOCHEMISTRY .2. PHOTOCHEMISTRY OF AZOBENZENE AND ITS DERIVATIVES [J].
GRIFFITHS, J .
CHEMICAL SOCIETY REVIEWS, 1972, 1 (04) :481-493
[4]   PHOTORESPONSIVE BEHAVIOR OF AZOBENZENE-BASED (METH)ACRYLIC (CO)POLYMERS IN THIN-FILMS [J].
HAITJEMA, HJ ;
VONMORGEN, GL ;
TAN, YY ;
CHALLA, G .
MACROMOLECULES, 1994, 27 (21) :6201-6206
[5]   Single-molecule optomechanical cycle [J].
Hugel, T ;
Holland, NB ;
Cattani, A ;
Moroder, L ;
Seitz, M ;
Gaub, HE .
SCIENCE, 2002, 296 (5570) :1103-1106
[6]  
Ionita I., 2003, OVIDIUS U ANN CHEM, VXIV, P118
[7]  
Krzysztof J., 2002, MAT SCI, V20, P45
[8]   PHOTOCHEMISTRY OF AZOBENZENE-CONTAINING POLYMERS [J].
KUMAR, GS ;
NECKERS, DC .
CHEMICAL REVIEWS, 1989, 89 (08) :1915-1925
[9]   Photoinduced motions in azo-containing polymers [J].
Natansohn, A ;
Rochon, P .
CHEMICAL REVIEWS, 2002, 102 (11) :4139-4175
[10]  
PARMAR JS, 1991, HIGH PERFORM POLYM, V3, P89