5-Hydroxymethyl furfural (HMF) and furfurals are DOE-listed platform chemicals that can be derived from the renewable carbon in the lignocellulosic biomasses and have the potential to replace petroleum-derived alternatives. High substrate cost and use of expensive solvents limit the economic feasibility of bio-based HMF production on an industrially relevant scale. The study presents an experimental optimized condition that maximizes the chemical-free production of HMF and furfurals without lowering the yield of total fermentable sugars from Saccharum bagasse. Hydrothermal pretreatment at 210 degrees C for 15 min yielded approximately 10%, 12%, and 46% of HMF, furfurals, and fermentable sugars per gram of dry biomass, respectively. Additionally, the study proposes a consolidated bioprocess model to produce and recover four high-value bioproducts i.e., HMF, furfurals, ethanol, and acetic acid based on the experimental results and evaluates its technoeconomic feasibility considering HMF as the main product. The minimum selling price (MSP) of HMF was estimated to be 930.6 USD/ t which is competitive with its petroleum-derived precursor alternative p-xylene (1,113 USD/t). The sensitivity analysis performed for the process parameters suggests that pretreatment cost and revenues from coproducts immensely influence the MSP of HMF. The preliminary technoeconomic analysis performed on the consolidated bioprocess design indicates that additional revenue streams from diversified coproducts in biorefineries aid in lowering the MSP of high-value bioproducts.
机构:
Lakehead Univ, Fac Nat Resources Management, Braun Bldg,BB1007D-955 Oliver Rd, Thunder Bay, ON P7B 5E, CanadaLakehead Univ, Fac Nat Resources Management, Braun Bldg,BB1007D-955 Oliver Rd, Thunder Bay, ON P7B 5E, Canada
Dessbesell, Luana
Xu, Chunbao
论文数: 0引用数: 0
h-index: 0
机构:
Western Univ, Dept Chem & Biochem Engn, ICFAR, Rm 108 & Room CMLP 2335, London, ON N6A 5B9, CanadaLakehead Univ, Fac Nat Resources Management, Braun Bldg,BB1007D-955 Oliver Rd, Thunder Bay, ON P7B 5E, Canada
Xu, Chunbao
论文数: 引用数:
h-index:
机构:
Pulkki, Reino
Leitch, Mathew
论文数: 0引用数: 0
h-index: 0
机构:
Lakehead Univ, Fac Nat Resources Management, Braun Bldg,BB1007D-955 Oliver Rd, Thunder Bay, ON P7B 5E, CanadaLakehead Univ, Fac Nat Resources Management, Braun Bldg,BB1007D-955 Oliver Rd, Thunder Bay, ON P7B 5E, Canada
Leitch, Mathew
Mahmood, Nubla
论文数: 0引用数: 0
h-index: 0
机构:
Western Univ, Dept Chem & Biochem Engn, ICFAR, Rm 108 & Room CMLP 2335, London, ON N6A 5B9, CanadaLakehead Univ, Fac Nat Resources Management, Braun Bldg,BB1007D-955 Oliver Rd, Thunder Bay, ON P7B 5E, Canada
机构:
North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USANorth Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
Ou, Longwen
Dou, Chang
论文数: 0引用数: 0
h-index: 0
机构:
North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USANorth Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
Dou, Chang
Yu, Ju-Hyun
论文数: 0引用数: 0
h-index: 0
机构:
Korea Res Inst Chem Technol, Ctr Biobased Chem, Daejeon, South KoreaNorth Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
Yu, Ju-Hyun
Kim, Hoyong
论文数: 0引用数: 0
h-index: 0
机构:
Korea Res Inst Chem Technol, Ctr Biobased Chem, Daejeon, South KoreaNorth Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
Kim, Hoyong
Park, Yong-Cheol
论文数: 0引用数: 0
h-index: 0
机构:
Kookmin Univ, Dept Bio & Fermentat Convergence Technol, Seoul, South Korea
Kookmin Univ, BK21 Plus Program, Seoul, South KoreaNorth Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
Park, Yong-Cheol
Lee, Eun Yeol
论文数: 0引用数: 0
h-index: 0
机构:
Kyung Hee Univ, Dept Chem Engn, Seoul, South KoreaNorth Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
机构:
Michigan Technol Univ, Dept Chem Engn, 1400 Townsend Dr, Houghton, MI 49931 USA
Michigan Technol Univ, Sustainable Futures Inst, 1400 Townsend Dr, Houghton, MI 49931 USAMichigan Technol Univ, Dept Chem Engn, 1400 Townsend Dr, Houghton, MI 49931 USA
Gracida-Alvarez, Ulises R.
Winjobi, Olumide
论文数: 0引用数: 0
h-index: 0
机构:
Michigan Technol Univ, Dept Chem Engn, 1400 Townsend Dr, Houghton, MI 49931 USA
Michigan Technol Univ, Sustainable Futures Inst, 1400 Townsend Dr, Houghton, MI 49931 USAMichigan Technol Univ, Dept Chem Engn, 1400 Townsend Dr, Houghton, MI 49931 USA
Winjobi, Olumide
Sacramento-Rivera, Julio C.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Autonoma Yucatan, Fac Chem Engn, Periferico Norte Km 33-5,Tablaje Catastral 13615, Merida 97203, Yucatan, MexicoMichigan Technol Univ, Dept Chem Engn, 1400 Townsend Dr, Houghton, MI 49931 USA
Sacramento-Rivera, Julio C.
Shonnard, David R.
论文数: 0引用数: 0
h-index: 0
机构:
Michigan Technol Univ, Dept Chem Engn, 1400 Townsend Dr, Houghton, MI 49931 USA
Michigan Technol Univ, Sustainable Futures Inst, 1400 Townsend Dr, Houghton, MI 49931 USAMichigan Technol Univ, Dept Chem Engn, 1400 Townsend Dr, Houghton, MI 49931 USA
机构:
Inner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R ChinaInner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R China
Zhong, Yuan
Liu, Zhechen
论文数: 0引用数: 0
h-index: 0
机构:
Inner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R ChinaInner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R China
Liu, Zhechen
Wang, Yamei
论文数: 0引用数: 0
h-index: 0
机构:
Inner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R ChinaInner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R China
Wang, Yamei
Zhang, Xiaotao
论文数: 0引用数: 0
h-index: 0
机构:
Inner Mongolia Agr Univ, Coll Sci, Hohhot 010018, Peoples R China
Inner Mongolia Key Lab Sandy Shrubs Fibrosis & Ene, Hohhot 010018, Peoples R China
Natl Forestry Grassland Engn Technol Res Ctr Effic, Hohhot 010018, Peoples R ChinaInner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R China
Zhang, Xiaotao
Wang, Ximing
论文数: 0引用数: 0
h-index: 0
机构:
Inner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R China
Inner Mongolia Key Lab Sandy Shrubs Fibrosis & Ene, Hohhot 010018, Peoples R China
Natl Forestry Grassland Engn Technol Res Ctr Effic, Hohhot 010018, Peoples R ChinaInner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R China