Ionic liquids in solid-phase extraction

被引:93
作者
Fontanals, Nuria [1 ]
Borrull, Francesc [1 ]
Marce, Rosa M. [1 ]
机构
[1] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, Tarragona 43007, Spain
关键词
Immobilizing support; Interaction mechanism; Ionic liquid (IL); Polymer-based support; Reversed phase (RP); Solid-phase extraction (SPE); Sorbent; Strong anion exchange (SAX); Supported ionic-liquid phase (SILP); Silica-based support; ENVIRONMENTAL WATER SAMPLES; PI-COMPLEXING SORBENTS; ACID METHYL-ESTERS; MICROEXTRACTION TECHNIQUES; FUNCTIONALIZED SILICA; SELECTIVE RECOGNITION; ANALYTICAL-CHEMISTRY; POLYMER SORBENT; SEPARATION; CHROMATOGRAPHY;
D O I
10.1016/j.trac.2012.08.010
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Supported ionic-liquid phases (SILPs), which favorably combine the properties of ionic liquids (ILs) with the advantages of solid supports, were presented in 2009 as an alternative material for solid-phase extraction (SPE). Since then, the number of SILPs used as SPE materials has increased and the results are promising. This report covers various aspects of SILPs: (1) the procedure for their preparation, which clearly depends on the support (based on silica or polymer) where the ILs are immobilized; (2) their interaction mechanisms, which are strongly linked to the SPE protocol and the target analytes; and, (3) their fields of application with a number of selected examples. This is the first review that exclusively describes all SILPs that have been developed to date as sorbents in SPE. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:15 / 26
页数:12
相关论文
共 53 条
[1]   The roles of ionic liquids in sorptive microextraction techniques [J].
Aguilera-Herrador, Eva ;
Lucena, Rafael ;
Cardenas, Soledad ;
Valcarcel, Miguel .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2010, 29 (07) :602-616
[2]   Ionic liquids in analytical chemistry [J].
Anderson, Jared L. ;
Armstrong, Daniel W. ;
Wei, Guor-Tzo .
ANALYTICAL CHEMISTRY, 2006, 78 (09) :2892-2902
[3]   Separation and preconcentration of Pb(II) using ionic liquid-modified silica and its determination by flame atomic absorption spectrometry [J].
Ayata, Sevda ;
Bozkurt, Serap Seyhan ;
Ocakoglu, Kasim .
TALANTA, 2011, 84 (01) :212-215
[4]   Molecularly-imprinted polymers: useful sorbents for selective extractions [J].
Beltran, A. ;
Borrull, F. ;
Cormack, P. A. G. ;
Marce, R. M. .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2010, 29 (11) :1363-1375
[5]   Ionic liquids in separation techniques [J].
Berthod, A. ;
Ruiz-Angel, Mt ;
Carda-Broch, S. .
JOURNAL OF CHROMATOGRAPHY A, 2008, 1184 (1-2) :6-18
[6]   Separation of phenolic acids from natural plant extracts using molecularly imprinted anion-exchange polymer confined ionic liquids [J].
Bi, Wentao ;
Tian, Minglei ;
Row, Kyung Ho .
JOURNAL OF CHROMATOGRAPHY A, 2012, 1232 :37-42
[7]   Selective extraction and separation of oxymatrine from Sophora flavescens Ait. extract by silica-confined ionic liquid [J].
Bi, Wentao ;
Tian, Minglei ;
Row, Kyung Ho .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2012, 880 :108-113
[8]   Solid-phase Extraction of Liquiritin and Glycyrrhizin from Licorice using Porous Alkyl-pyridinium Polymer Sorbent [J].
Bi, Wentao ;
Tian, Minglei ;
Row, Kyung Ho .
PHYTOCHEMICAL ANALYSIS, 2010, 21 (05) :496-501
[9]   Solid-phase extraction of matrine and oxymatrine from Sophora Flavescens Ait using amino-imidazolium polymer [J].
Bi, Wentao ;
Tian, Minglei ;
Row, Kyung Ho .
JOURNAL OF SEPARATION SCIENCE, 2010, 33 (12) :1739-1745
[10]   Comparison of different imidazolium supported ionic liquid polymeric phases with strong anion-exchange character for the extraction of acidic pharmaceuticals from complex environmental samples [J].
Bratkowska, Dominika ;
Fontanals, Nuria ;
Ronka, Sylwia ;
Trochimczuk, Andrzej W. ;
Borrull, Francesc ;
Marce, Rosa M. .
JOURNAL OF SEPARATION SCIENCE, 2012, 35 (15) :1953-1958