Cyclic Silylhydroxylamines and 1,3-Diaza-2-Silacyclopentane - Lithium Derivatives and Reactions

被引：1

作者：

Diedrich, Friedhelm ^{[1
]}

Ebker, Christina ^{[1
]}

Klingebiel, Uwe ^{[1
]}

机构：

[1] Univ Gottingen, Inst Inorgan Chem, D-37077 Gottingen, Germany

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 169卷 / 01期

关键词：

Silylhydroxylamines; Lithium silylhydroxylamides; Diaza-silacyclopentanes; X-ray structures;

D O I：

10.1080/10426500108546636

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lithium derivatives of silylhydroxylamines are used for more than thirty years. Now we are able to present the first crystal structures. Lithium is bonded side on and end on in these silylhydroxylamides. Depending on the reaction conditions and the bulkiness of the substituents dimeric, trimeric, and tetrameric oligomers are found. Fluoro-functional bis(silyl)hydroxylamines are excellent precursors for rings. By-products of the syntheses of bis(silyl)hydroxylamines are N, bis(silyl)ethylendiamines, which are easily cyclized forming l, 2-diaza-2-silacyclopentanes. Reactions and X-ray analyses are discussed.

引用

页码：253 / 256

页数：4