Chiral synthons from carvone .24. Photochemical rearrangements of chiral bicyclo[2.2.2]oct-5-en-2-ones

被引：3

作者：

Srikrishna, A

Danieldoss, S

机构：

[1] Department of Organic Chemistry, Indian Institute of Science

来源：

SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 04期

关键词：

D O I：

10.1080/00397919708003339

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photochemical oxadi-pi-methane rearrangement (1,2-acyl shift) of the chiral bicyclo[2.2.2]oct-5-en-2-ones 2 and 3 furnishes the tricyclic ketones 5 and 6, whereas the 1,3-acyl shift generates the cyclobutanones 7 and 8 respectively.

引用

页码：655 / 661

页数：7

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