Synthesis and Characterizations of Melamine-Based Epoxy Resins

被引:51
作者
Ricciotti, Laura [1 ]
Roviello, Giuseppina [1 ]
Tarallo, Oreste [2 ]
Borbone, Fabio [2 ]
Ferone, Claudio [1 ]
Colangelo, Francesco [1 ]
Catauro, Michelina [3 ]
Cioffi, Raffaele [1 ]
机构
[1] Univ Napoli Parthenope, Dipartimento Ingn, INSTM Res Grp Napoli Parthenope, Ctr Direzionale Napoli, Isola C4, I-80143 Naples, Italy
[2] Univ Naples Federico II, Dipartimento Sci Chim, I-80126 Naples, Italy
[3] Univ Naples 2, Dipartimento Ingn Ind & Informaz, I-81031 Aversa, Italy
关键词
epoxy resin; melamine; glycidyl derivative; IR; DSC; DMA; glass transition; crosslinking reaction; synthesis; ELECTRONIC-PROPERTIES; REACTIVE SOLVENTS;
D O I
10.3390/ijms140918200
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A new, easy and cost-effective synthetic procedure for the preparation of thermosetting melamine-based epoxy resins is reported. By this innovative synthetic method, different kinds of resins can be obtained just by mixing the reagents in the presence of a catalyst without solvent and with mild curing conditions. Two types of resins were synthesized using melamine and a glycidyl derivative (resins I) or by adding a silane derivative (resin II). The resins were characterized by means of chemical-physical and thermal techniques. Experimental results show that all the prepared resins have a good thermal stability, but differ for their mechanical properties: resin I exhibits remarkable stiffness with a storage modulus value up to 830 MPa at room temperature, while lower storage moduli were found for resin II, indicating that the presence of silane groups could enhance the flexibility of these materials. The resins show a pot life higher than 30 min, which makes these resins good candidates for practical applications. The functionalization with silane terminations can be exploited in the formulation of hybrid organic-inorganic composite materials.
引用
收藏
页码:18200 / 18214
页数:15
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