Manipulating Crystal Orientation of Poly(ethylene oxide) by Nanopores

被引:69
作者
Guan, Yu [1 ]
Liu, Guoming [1 ]
Gao, Peiyuan [2 ]
Li, Li [3 ]
Ding, Guqiao [4 ]
Wang, Dujin [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
[4] Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, State Key Lab Funct Mat Informat, Shanghai 200050, Peoples R China
基金
中国国家自然科学基金;
关键词
SYNDIOTACTIC POLYSTYRENE; CYLINDRICAL NANOPORES; CRYSTALLIZATION; TEMPLATES; ALUMINA; NANOCOMPOSITES; POLYETHYLENE; COPOLYMERS;
D O I
10.1021/mz300592v
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The confined crystallization behavior of a low molecular weight monodisperse polyethylene oxide (PEO) in anodic alumina oxide (AAO) templates was investigated. Homogeneous nucleation of polymer in AAO templates was confirmed. Within AAO with diameter larger than the contour length of PEO chains, the "kinetics selective growth" crystallization mechanism was confirmed based on the observation that the chain axis preferentially aligned perpendicular to the pore axis. However, when AAO diameter further decreases to a value smaller than the contour length of PEO, unique orientation with chain axis aligned parallel to the pore axis was observed for the first time. The results were discussed based on the competition between thermodynamics and kinetics during the crystallization process.
引用
收藏
页码:181 / 184
页数:4
相关论文
共 24 条
[11]   The Crystallization of Confined Polymers and Block Copolymers Infiltrated Within Alumina Nanotube Templates [J].
Michell, Rose Mary ;
Lorenzo, Arnaldo T. ;
Mueller, Alejandro J. ;
Lin, Ming-Champ ;
Chen, Hsin-Lung ;
Blaszczyk-Lezak, Iwona ;
Martin, Jaime ;
Mijangos, Carmen .
MACROMOLECULES, 2012, 45 (03) :1517-1528
[12]   Nucleation and crystallization in diblock and triblock copolymers [J].
Müller, AJ ;
Balsamo, V ;
Arnal, ML .
BLOCK COPOLYMERS II, 2005, 190 :1-63
[13]   Model polymer nanocomposites provide an understanding of confinement effects in real nanocomposites [J].
Rittigstein, Perla ;
Priestley, Rodney D. ;
Broadbelt, Linda J. ;
Torkelson, John M. .
NATURE MATERIALS, 2007, 6 (04) :278-282
[14]   Crystalline structures, melting, and crystallization of linear polyethylene in cylindrical nanopores [J].
Shin, Kyusoon ;
Woo, Euntaek ;
Jeong, Young Gyu ;
Kim, Chulkyu ;
Huh, June ;
Kim, Kwang-Woo .
MACROMOLECULES, 2007, 40 (18) :6617-6623
[15]   Polymer nanotubes by wetting of ordered porous templates [J].
Steinhart, M ;
Wendorff, JH ;
Greiner, A ;
Wehrspohn, RB ;
Nielsch, K ;
Schilling, J ;
Choi, J ;
Gösele, U .
SCIENCE, 2002, 296 (5575) :1997-1997
[16]   Coherent kinetic control over crystal orientation in macroscopic ensembles of polymer nanorods and nanotubes [J].
Steinhart, Martin ;
Goering, Petra ;
Dernaika, Haissam ;
Prabhukaran, Munusamy ;
Goesele, Ulrich ;
Hempel, Elke ;
Thurn-Albrecht, Thomas .
PHYSICAL REVIEW LETTERS, 2006, 97 (02)
[17]   Supramolecular Organization of Polymeric Materials in Nanoporous Hard Templates [J].
Steinhart, Martin .
SELF-ASSEMBLED NANOMATERIALS II: NANOTUBES, 2008, 220 :123-187
[18]  
Stranski IN, 1934, Z PHYS CHEM B-CHEM E, V26, P100
[19]   STRUCTURAL STUDIES OF POLYETHERS, (-(CH2)M-O-)N .10. CRYSTAL-STRUCTURE OF POLY(ETHYLENE OXIDE) [J].
TAKAHASHI, Y ;
TADOKORO, H .
MACROMOLECULES, 1973, 6 (05) :672-675
[20]   Confined Crystallization of Polyethylene Oxide in Nanolayer Assemblies [J].
Wang, Haopeng ;
Keum, Jong K. ;
Hiltner, Anne ;
Baer, Eric ;
Freeman, Benny ;
Rozanski, Artur ;
Galeski, Andrzej .
SCIENCE, 2009, 323 (5915) :757-760